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Perkin Transactions 1 1972-2002 logo

Year 1987
Main Index

Front matter

pg P001; DOI:
10.1039/P198700FP001
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Metacyclophanes and related compounds. Part 16. Preparation of 8-fluoro-t-butyl[2.2]metacyclophanes and their treatment with aluminium chloride–nitromethane in benzene
Takehiko Yamato Takashi Arimura and Masashi Tashiro
pg 1; DOI:
10.1039/P19870000001
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Index pages

pg A003; DOI:
10.1039/P198700BA003
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Synthesis of oligosaccharides corresponding to biological repeating units of Shigella flexneri variant Y polysaccharide. Part 1. Overall strategy, synthesis of a key trisaccharide intermediate, and synthesis of a pentasaccharide
B. Mario Pinto David G. Morissette and David R. Bundle
pg 9; DOI:
10.1039/P19870000009
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Photochemical cycloadditions of 1,3-dioxoles to anisole
Jochen Mattay Jan Runsink Joseph A. Piccirilli Arnold W. H. Jens and Jan Cornelisse
pg 15; DOI:
10.1039/P19870000015
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Model studies of histrionicotoxin. The synthesis of the 1-azaspiro[5.5]undecane rings system from carbohydrate starting materials
Keith Brewster John M. Harrison Thomas D. Inch and Nancy Williams
pg 21; DOI:
10.1039/P19870000021
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Biosynthesis of the polyether ionophore antibiotic monensin A: assignment of the carbon-13 and proton n.m.r. spectra of monensin A by two-dimensional spectroscopy. Incorporation of oxygen-18 labelled molecular oxygen
Abid A. Ajaz John A. Robinson and David L. Turner
pg 27; DOI:
10.1039/P19870000027
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14-Methyl steroids. Part 4. Synthesis of 14-methylestradiol and related 14-methyl-19-norsteroids
James R. Bull Jan Floor and Mark A. Sefton
pg 37; DOI:
10.1039/P19870000037
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Preparation and properties of 7-formamido cephalosporins
Angela W. Guest Clive L. Branch Stephen C. Finch Arun C. Kaura Peter H. Milner Michael J. Pearson Roger J. Ponsford and Terence C. Smale
pg 45; DOI:
10.1039/P19870000045
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Inter- and intra-molecular aromatic N-substitution by arylnitrenium–aluminium chloride complexes generated from aryl azides in the presence of aluminium chloride
Hiroshi Takeuchi Munenori Maeda Michiharu Mitani and Kikuhiko Koyama
pg 57; DOI:
10.1039/P19870000057
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Synthesis of C-19-chiral steroids. Preparation of (19R); (19S) and (19RS)-3-hydroxy[19-2H1,19-3H1] androst-5-en-17-ones
Thangavel Arunachalam Enzo Santaniello Kundan Patel and Eliahu Caspi
pg 61; DOI:
10.1039/P19870000061
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Asymmetric oxidation of sulphides to sulphoxides catalysed by titanium complexes of N-salicylidene-L-amino acids
Stefano Colonna Amedea Manfredi Massimo Spadoni Luigi Casella and Michele Gullotti
pg 71; DOI:
10.1039/P19870000071
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Hydrolysis products of flavins (isoalloxazines)
Takashi Harayama Yasuhiro Tezuka Tooru Taga and Fumio Yoneda
pg 75; DOI:
10.1039/P19870000075
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Photolysis of 2,3-epoxy-7,7-diphenylbicyclo[3.2.0]heptan-6-ones and 2-exo, 3-exo-dihydroxy-7,7-diphenylbicyclo[3.2.0]heptan-6-one
H. Geoff Davies Shahzad S. Rahman Stanley M. Roberts Basil J. Wakefield and John A. Winders
pg 85; DOI:
10.1039/P19870000085
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Chiral route to cis-caronaldehyde from D-mannitol
Seiichi Takano Ayako Kurotaki Michiyasu Takahashi and Kunio Ogasawara
pg 91; DOI:
10.1039/P19870000091
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Thermal reactivity of 4-substituted- and 4-substituted-2-phenyl-benzenesulphenanilides
Luisa Benati Pier Carlo Montevecchi and Piero Spagnolo
pg 99; DOI:
10.1039/P19870000099
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Application of 2H n.m.r. spectroscopy to study the incorporation of enantiomeric 2H-labelled cadaverines into quinolizidine alkaloids
Alison M. Fraser and David J. Robins
pg 105; DOI:
10.1039/P19870000105
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Inhibitors of human leucocyte elastase. Peptides incorporating an -azanorvaline residue or a thiomethylene linkage in place of a peptide bond
Anand S. Dutta Michael B. Giles James J. Gormley Joseph C. Williams and Edward J. Kusner
pg 111; DOI:
10.1039/P19870000111
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Preparation of acyltetronic acids using t-butyl acetothioacetate: total synthesis of the fungal metabolites carolic, carlosic, and carlic acids
Paul M. Booth Christina M. J. Fox and Steven V. Ley
pg 121; DOI:
10.1039/P19870000121
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Use of S-t-butyl acetothioacetate in the preparation of milbemycin seco-analogues
Trafford Clarke and Steven V. Ley
pg 131; DOI:
10.1039/P19870000131
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Synthesis of stable analogues of TXA2
Elizabeth H. Evans Alan T. Hewson Lorraine A. March Ian W. Nowell and Alan H. Wadsworth
pg 137; DOI:
10.1039/P19870000137
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Reactions of tris(2,6-dimethoxyphenyl)phosphine with epoxides
Masanoir Wada and Aki Tsuboi
pg 151; DOI:
10.1039/P19870000151
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Aspidosperma alkaloids. Conversion of tabersonine into vindoline
Bruno Danieli Giordano Lesma Giovanni Palmisano and Renata Riva
pg 155; DOI:
10.1039/P19870000155
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Synthesis of model compounds of some biogenetic precursors of aflatoxin B1
Charles P. Gorst-Allman and Pieter S. Steyn
pg 163; DOI:
10.1039/P19870000163
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Ring-C aromatic steroids. Part 5. C-17 Hydroxylation and side-chain degradation of 18-nor-17(H)- and -17(H)-pregna-4,8,11,13-tetraene-3,20-dione. X-Ray structure of 17-hydroxy-18-nor-17(H)-pregna-4,8,11,13-tetraene-3,20-dione
Peter M. Burden H. T. Andrew Cheung Thomas R. Watson George Ferguson and Patricia F. Seymour
pg 169; DOI:
10.1039/P19870000169
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Aaptamines. Novel benzo[de][1,6]naphthyridines from the Okinawan marine sponge Aaptos aaptos
Hideshi Nakamura Jun'ichi Kobayashi Yasushi Ohizumi and Yoshimasa Hirata
pg 173; DOI:
10.1039/P19870000173
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Pyrrolizidine alkaloid biosynthesis. Incorporation of 13C-labelled precursors into rosmarinine
Henry A. Kelly and David J. Robins
pg 177; DOI:
10.1039/P19870000177
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Studies on selected transformations of some fluoromethanephosphonate esters
G. Michael Blackburn David Brown Stephen J. Martin and Martin J. Parratt
pg 181; DOI:
10.1039/P19870000181
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10-Thia-anthracenes. Part 3. A re-examination of the reaction of 9-phenylthioxanthylium salt and phenyl-lithium
Mikio Hori Tadashi Kataoka Hiroshi Shimizu Masatoshi Ban and Hitoshi Matsushita
pg 187; DOI:
10.1039/P19870000187
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On the preparation and chemical reactivity of 2-benzopyrylium-4-olate
Peter G. Sammes and Richard J. Whitby
pg 195; DOI:
10.1039/P19870000195
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Organic heterocyclothiazenes. Part 1. The trithiadiazepine and trithiatriazepine ring systems
Stephen T. A. K. Daley and Charles W. Rees
pg 203; DOI:
10.1039/P19870000203
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Organic heterocyclothiazenes. Part 2. Reaction of tetrasulphur tetranitride with phenylacetylene and diphenylacetylene
Stephen T. A. K. Daley and Charles W. Rees
pg 207; DOI:
10.1039/P19870000207
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Organic heterocyclothiazenes. Part 3. Synthesis and structure of 1,3,5,2,4-trithiadiazepines
Janet L. Morris and Charles W. Rees
pg 211; DOI:
10.1039/P19870000211
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Organic heterocyclothiazenes. Part 4. Chemistry of 1,3,5,2,4-trithiadiazepines
Janet L. Morris and Charles W. Rees
pg 217; DOI:
10.1039/P19870000217
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An approach to the construction of aromatic steroids using electrocyclic ring closure
Thomas L. Gilchrist and John E. Stanford
pg 225; DOI:
10.1039/P19870000225
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Naturally occurring dibenzofurans. Part 9. A convenient synthesis of phthalides: the synthesis of methyl di-O-methylporphyrilate
Melvyn V. Sargent
pg 231; DOI:
10.1039/P19870000231
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Stereochemical studies. Part 103. Saturated heterocycles part 107. Preparation of 3-mono- and 2,3-di-substituted pyrimidin-4(3H)-ones in retro- Diels–Alder reactions. The correct 1,2-disubstituted structure of the compounds previously described as 2,3-disubstituted derivatives
Géza Stájer Angela E. Szabó Gábor Bernáth and Pál Sohár
pg 237; DOI:
10.1039/P19870000237
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The chemistry of pentavalent organobismuth reagents. Part 7. The possible role of radical mechanisms in the phenylation process for bismuth(V), and related lead(IV), lodine(III), and antimony(V) reagents
Derek H. R. Barton Jean-Pierre Finet Charles Giannotti and Frank Halley
pg 241; DOI:
10.1039/P19870000241
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The chemistry of pentavalent organobismuth reagents. Part 8. Phenylation and oxidation of alcohols by tetraphenylbismuth esters
Derek H. R. Barton Jean-Pierre Finet William B. Motherwell and Clotilde Pichon
pg 251; DOI:
10.1039/P19870000251
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Synthesis of heterocycles via enamines. Part 12. Intramolecular additions of nucleophiles to 1,4-dihydropyrimidine-2(3H)-thione derivatives: single-step synthesis of condensed heterocyclic compounds
Harjit Singh and Subodh Kumar
pg 261; DOI:
10.1039/P19870000261
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Synthetic and biosynthetic studies of porphyrins. Part 7. The action of coproporphyrinogen oxidase on coproporphyrinogen-IV: syntheses of protoporphyrin-XIII, mesoporphyrin XIII, and related tricarboxylic porphyrins
Hassan M. G. Al-Hazimi Anthony H. Jackson David W. Knight and Timothy D. Lash
pg 265; DOI:
10.1039/P19870000265
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Synthetic and biosynthetic studies of porphyrins. Part 8. Syntheses of hepta-, hexa-, and penta-carboxylic porphyrins related to uroporphyrin-I
Anthony H. Jackson and Damrus Supphayen
pg 277; DOI:
10.1039/P19870000277
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Synthetic and biosynthetic studies of porphyrins. Part 9. Synthesis of isocoproporphyrin, dehydroisocoproporphyrin, and de-ethylisocoproporphyrin
Anthony H. Jackson Timothy D. Lash and David J. Ryder
pg 287; DOI:
10.1039/P19870000287
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Synthetic and biosynthetic studies of porphyrins. Part 10. Syntheses of porphyrins with acetic, propionic, and butyric acid side-chains for biosynthetic studies
Anthony H. Jackson Ravindra K. Pandey and Kevin M. Smith
pg 299; DOI:
10.1039/P19870000299
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Synthetic and biosynthetic studies of porphyrins. Part 11. The synthesis of meso oxygenated protoporphyrins
Anthony H. Jackson K. R. Nagaraja Rao and Martyn Wilkins
pg 307; DOI:
10.1039/P19870000307
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Studies on pyrrolizidines and related compounds. Part 9. Rearrangement of 7a-trichloromethyl-2,3,5,6,7,7a-hexahydro-1H-pyrrolizine and related compounds: an alternative route to 5-substituted 1-azabicyclo[3.3.1]nonanes
Seiji Miyano Nobuko Mibu Michiko Irie Shinichiro Fujii Fumiko Fujisaki Nobuhiro Abe and Kunihiro Sumoto
pg 313; DOI:
10.1039/P19870000313
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Synthesis of the Mammea coumarins. Part 1. The coumarins of the mammea A, B, and C series
Leslie Crombie Raymond C. F. Jones and Christopher J. Palmer
pg 317; DOI:
10.1039/P19870000317
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Synthesis of the Mammea coumarins. Part 2. Experiments in the mammea E series and synthesis of mammea E/AC
Leslie Crombie Raymond C. F. Jones and Christopher J. Palmer
pg 333; DOI:
10.1039/P19870000333
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Synthesis of the Mammea coumarins. Part 3. The insecticidal coumarins of the mammea E series, mammea D/BB, and a dihydrocoumarin of the mammea C series
Leslie Crombie Raymond C. F. Jones and Christopher J. Palmer
pg 345; DOI:
10.1039/P19870000345
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Synthesis of the Mammea coumarins. Part 4. Stereochemical and regiochemical studies, and synthesis of (–)-mammea B/BB
Michael J. Begley Leslie Crombie Raymond C. F. Jones and Christopher J. Palmer
pg 353; DOI:
10.1039/P19870000353
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Photochemistry of the carbon–nitrogen double bond. Part 2. An investigation of the 3-methylenepropan-1-imine and 3-oxopropan-1-imine chromophores
Albert C. Pratt and Qais Abdul-Majid
pg 359; DOI:
10.1039/P19870000359
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Four isomeric 7-isopropyloctahydro-4H-inden-4-ones
Albert R. Matlin and William C. Agosta
pg 365; DOI:
10.1039/P19870000365
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Synthesis of triphenylene 1,2-oxide (1,2-epoxy-1,2-dihydrophenylene) and absolute configuration of the trans-1,2-dihydro diol metabolite of triphenylene. Crystal structure of (–)-(1R,2R)-trans-2-bromo-1-menthylxyacetoxy-1,2,3,4-tetrahydrotriphenylene
Derek R. Boyd Deirdre A. Kennedy John F. Malone Gerard A. O'Kane Dhiren T. Thakker Heruhiko Yagi and Donald M. Jerina
pg 369; DOI:
10.1039/P19870000369
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Nuclear magnetic resonance and conformational studies on monoacetylated methyl D-gluco- and D-galacto-pyranosides
Per-Erik Jansson Lennart Kenne and Elke Schweda
pg 377; DOI:
10.1039/P19870000377
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Preparation of aromatase inhibitors. Synthesis of 19,19-difluoro-4-hydroxyandrost-4-ene-3,17-dione and related compounds
John Mann and Barbara Pietrzak
pg 385; DOI:
10.1039/P19870000385
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Studies on the syntheses of heterocyclic compounds containing benzopyrone. Part 5. Total synthesis of fulvic acid
Masashige Yamauchi Sadamu Katayama Toshiharu Todoroki and Toshio Watanabe
pg 389; DOI:
10.1039/P19870000389
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Studies on the syntheses of heterocyclic compounds containing benzopyrone. Part 6. Biomimetic total synthesis of citromycetin
Masashige Yamauchi Sadamu Katayama and Toshio Watanabe
pg 395; DOI:
10.1039/P19870000395
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Base-promoted cyclisation of hydrazonoyl chlorides bearing an alkynylsulphonyl group
Luca Bruché and Gaetano Zecchi
pg 399; DOI:
10.1039/P19870000399
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Cyclo-octa[def]carbazole, a new heterocyclic paratropic ring system
Glynn Mitchell and Charles W. Rees
pg 403; DOI:
10.1039/P19870000403
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Photolysis of 1-aryl -1,2,3-triazoles; rearrangement via 1H-azirines
Glynn Mitchell and Charles W. Rees
pg 413; DOI:
10.1039/P19870000413
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The allyl group for protection in carbohydrate chemistry. Part 18. Allyl and benzyl ethers of myo-inositol. Intermediates for the synthesis of myo-inositol trisphosphates
Jill Gigg Roy Gigg Sheila Payne and Robert Conant
pg 423; DOI:
10.1039/P19870000423
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Synthesis of the phytoalexin ()-phaseollin: 3-phenylthiochromans as masked 2H-chromenes and o-prenyl phenols
Salah E. N. Mohamed Philip Thomas and Donald A. Whiting
pg 431; DOI:
10.1039/P19870000431
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Propentdyopents [5-(2-oxo-2H-pyrrol-5-ylmethylene)pyrrol-2(5H)-ones] and related compounds. Part 1. On the structure of the propentdyopent–alkanol adducts
Raymond Bonnett Michael J. Dimsdale and Gerald F. Stephenson
pg 439; DOI:
10.1039/P19870000439
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Dichroic dyestuffs. A synthesis of dialkyl-8-amino-1,4,5-trihydroxy- and 1,4,5,8-tetrahydroxy-anthraquinones
Anil Kumar James K. Sutherland and David J. Thompson
pg 445; DOI:
10.1039/P19870000445
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Photoresponsive crown ethers. Part 18. Photochemically switched-on crown ethers containing an intra-annular azo substituent and their application to membrane transport
Seiji Shinkai Kiminori Miyazaki and Osamu Manabe
pg 449; DOI:
10.1039/P19870000449
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Synthesis of 5-(1-substituted ethyl)uracil derivatives and some of their chemical and biological properties
A. Stanley Jones Michael J. McClean Martin J. Slater Richard T. Walker Jan Balzarini and Erik De Clercq
pg 457; DOI:
10.1039/P19870000457
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Condensed tannins: base-catalysed reactions of polymeric procyanidins with toluene--thiol. Lability of the interflavanoid bond and pyran ring
Peter E. Laks and Richard W. Hemingway
pg 465; DOI:
10.1039/P19870000465
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Microbial transformations of sesquiterpenoids: conversion of deoxyvulgarin by Rhizopus nigricans and Aspergillus ochraceous
José M. Arias José L. Bretón José A. Gavín Andrés García-Granados Antonio Martínez and M. Esther Onorato
pg 471; DOI:
10.1039/P19870000471
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Formation of cyclized, including 3,5-cyclosteroid, alkenes from ,-unsaturated Grignard reagents induced by elimination of a -alkoxy group
Peter M. Fischer and Merlin E. H. Howden
pg 475; DOI:
10.1039/P19870000475
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Syntheses of condensed polycyclic azonia aromatic compounds by photocyclization
Sadao Arai Tsuneo Takeuchi Masanori Ishikawa Tatsuo Takeuchi Masuo Yamazaki and Mitsuhiko Hida
pg 481; DOI:
10.1039/P19870000481
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Chiral dienolates: formation and stereoselective -alkylation of the lithium dienolate derived from (Z)-[(5-C5H5)Fe(CO)(PPh3)COCHCHMe]. X-Ray crystal structure of (RS)-(Z)-[(5-C5H5)Fe(CO)(PPh3)COCHCHMe]
Stephen G. Davies Robert J. C. Easton Kevin H. Sutton Jonathan C. Walker and Richard H. Jones
pg 489; DOI:
10.1039/P19870000489
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o-Nitrobenzylidene compounds. Part 3. Formation of 4-arylamino-3-methoxycinnoline 1-oxides from N-o-nitrobenzylideneanilines, cyanide ion, methanol: the intermediacy of 2-aryl-3-cyano-2H-indazole 1-oxides
David Johnston David M. Smith Thomas Shepherd and David Thompson
pg 495; DOI:
10.1039/P19870000495
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o-Nitrobenzylidene compounds. Part 4. The cyanide-induced cyclisation of o-acetamido-N-(o-nitrobenzylidene)anilines: an improved route to quinoxalino[2,3-c]cinnolines
Thomas Shepherd and David M. Smith
pg 501; DOI:
10.1039/P19870000501
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Polyaza heterocycles. Part 1. Halogenation of quinoxalino[2,3-c]cinnolines by hydrogen halides
Christopher Glidewell Thomas Shepherd and David M. Smith
pg 507; DOI:
10.1039/P19870000507
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The reaction of sodium 1,3-diphenyl-2-azapropenide with 1,2-epoxycyclohexane
Silvia Bradamante Raffaella Ferraccioli and Giorgio A. Pagani
pg 515; DOI:
10.1039/P19870000515
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Reduction and stereochemical studies through n.m.r. and X-ray techniques of indolo[2,1-b]quinazolines
Jan Bergman Ulf Tilstam and Karl-Wilhelm Törnroos
pg 519; DOI:
10.1039/P19870000519
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Synthesis of substrates of cyclic AMP-dependent protein kinase and use of their protected precursors for the convenient preparation of phosphoserine peptides
Leif Grehn Bengt Fransson and Ulf Ragnarsson
pg 529; DOI:
10.1039/P19870000529
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An approach to the total synthesis of the Prelog–Djerassi lactone
Keith Jones and William W. Wood
pg 537; DOI:
10.1039/P19870000537
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Synthesis and resolution of 3-substituted morpholine appetite suppressants and chiral synthesis via O-arylhomoserines
George R. Brown Alan J. Foubister and Donald Stribling
pg 547; DOI:
10.1039/P19870000547
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Hexahydro-1,4-oxazepines. Part 1. Synthesis by morpholine ring expansion
George R. Brown Alan J. Foubister and Brian Wright
pg 553; DOI:
10.1039/P19870000553
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Hexahydro-1,4-oxazepinos. Part 2. Unambiguous synthesis
George R. Brown Alan J. Foubister and Brian Wright
pg 557; DOI:
10.1039/P19870000557
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Carbon–carbon bond formation using hypervalent iodine under Lewis acid conditions: scope of the method for the synthesis of butane-1,4-diones
Robert Moriarty Om Prakash and Michael P. Duncan
pg 559; DOI:
10.1039/P19870000559
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The Hantzsch synthesis with salicylaldehyde revised. On the formation of bridged tetrahydropyridine derivatives
Jan Svtlík Frantiek Tureek and Vladimír Hanu
pg 563; DOI:
10.1039/P19870000563
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Ketene. Part 25. Mechanistic studies of the reaction of nitrile oxides with ketenes
Andrew R. Evans and Giles A. Taylor
pg 567; DOI:
10.1039/P19870000567
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Structure elucidation of the binary indole alkaloid uncaramine
Alberto Arnone Gianluca Nasini and Lucio Merlini
pg 571; DOI:
10.1039/P19870000571
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Isolation and identification of arsenic-containing ribofuranosides and inorganic arsenic from Japanese edible seaweed Hizikia fusiforme
John S. Edmonds Masatoshi Morita and Yasuyuki Shibata
pg 577; DOI:
10.1039/P19870000577
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Studies on sugar nitro-olefins. Part 7. Synthesis of 3-(alditol-1-yl)-1,2,3,5,6,7-hexahydro- and -1,5,6,7-tetrahydro-indol-4-ones. X-Ray molecular structure of (3S)-3-(1,2,3,4,5-penta-O-acetyl-D-galacto-pentitol-1-yl)-1,2,3,5,6,7-hexahydroindol-4-one
María J. Diánez José Galán Antonio Gómez-Sánchez Amparo López-Castro and Manuel Rico
pg 581; DOI:
10.1039/P19870000581
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Reaction of [arylthio(chloro)methyl]trimethylsilanes with arenes and alk-1-enes in the presence of Lewis acid: syntheses of [aryl(arylthio)methyl]- and (1-arylthioalk-3-enyl)-trimethylsilanes
Hiroyuki Ishibashi Hiroshi Nakatani Yoshizumi Umei Wako Yamamoto and Masazumi Ikeda
pg 589; DOI:
10.1039/P19870000589
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The synthesis of some cholesterol derivatives as probes for mechanisms of cholesterol metabolism
Linda Brown William J. S. Lyall Colin J. Suckling and Keith E. Suckling
pg 595; DOI:
10.1039/P19870000595
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The preparation and absolute configuration of the optically active forms of the diastereoisomers of 2-(1-phenylethyl)amino-1-phenylethanol and their use as chiral auxiliaries in the asymmetric reduction of acetophenone with modified lithium aluminium hydrides
Scott W. Garry and Douglas G. Neilson
pg 601; DOI:
10.1039/P19870000601
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1,3-Dipolar cycloaddition reactions of nitrilium betaines with aryl thiocyanates and selenocyanates
Derek J. Greig Douglas G. Hamilton Michael McPherson R. Michael Paton and John Crosby
pg 607; DOI:
10.1039/P19870000607
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Synthesis and adhesive studies of marine polypeptides
Hiroyuki Yamamoto
pg 613; DOI:
10.1039/P19870000613
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Cyanide substitution in aryl halides by copper(I) complexes derived from formamide and from formaldehyde oxime
Joseph A. Connor Danuta Gibson and Raymond Price
pg 619; DOI:
10.1039/P19870000619
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Heteroatom rearrangements. Extension to aliphatic carboxylic acids
Masataka Yokoyama Kenzi Sato Hideo Tateno and Hidekatsu Hatanaka
pg 623; DOI:
10.1039/P19870000623
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Triterpenoid glycosides of Corchorus acutangulus Lam.
Shashi B. Mahato and Bikas C. Pal
pg 629; DOI:
10.1039/P19870000629
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Spirocyclic penicillins
George Burton and Frank P. Harrington
pg 635; DOI:
10.1039/P19870000635
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The Hantzsch thiazole synthesis under acidic conditions: change of regioselectivity
(Miss) Susan E. Bramley Viscount Dupplin Dhanesh G. C. Goberdhan and G. Denis Meakins
pg 639; DOI:
10.1039/P19870000639
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Diazotization and Sandmeyer reactions of arylamines in poly(ethylene glycol)–methylene dichloride: usefulness of PEG in synthetic reactions
Nobutaka Suzuki Terukazu Azuma Yoshihiro Kaneko Yasuji Izawa Hideo Tomioka and Tateo Nomoto
pg 645; DOI:
10.1039/P19870000645
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Preparation and n.m.r. spectra of some hydrazono-malonates and -crotonates
Jacqueline J. Lyons and Hamish McNab
pg 649; DOI:
10.1039/P19870000649
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Synthesis of pyrrolo[1,2-c]imidazol-5-one, pyrrolo[1,2-a]imidazol-5-one and pyrrolo[1,2-b]pyrazol-6-one (three isomeric azapyrrolizinones), by pyrolysis of Meldrum's acid derivatives
Hamish McNab
pg 653; DOI:
10.1039/P19870000653
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An analysis of the n.m.r. spectra (1H, 13C, and, in part 15N and 17O) of pyrrolizin-3-one, and of its aza-derivatives pyrrolo[1,2-c]imidazol-5-one, pyrrolo[1,2-a]imidazol-5-one and pyrrolo[1,2-b]pyrazol-6-one
Hamish McNab
pg 657; DOI:
10.1039/P19870000657
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Dichloromethylenation of sugar -lactones: a stereospecific synthesis of L-(+)-muscarine and L-(+)-epimuscarine toluene-p-sulphonates
Alphonse Bandzouzi and Yves Chapleur
pg 661; DOI:
10.1039/P19870000661
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Antitumour imidazotetrazines. Part 12. Reactions of mitozolomide and its 3-alkyl congeners with oxygen, nitrogen, halogen, and carbon nucleophiles
Ghouse Unissa Baig and Malcolm F. G. Stevens
pg 665; DOI:
10.1039/P19870000665
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Studies on the chemical constituents of rutaceous plants. Part 62. Efficient synthesis of fagaronine, a phenolic benzo[c]phenanthridine alkaloid with antileukaemic activity
Hisashi Ishii Ih-Sheng Chen and Tsutomu Ishikawa
pg 671; DOI:
10.1039/P19870000671
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Chemical transformation of protoberberines. Part 10. A novel synthesis of sanguilutine and dihydrosanguilutine, fully aromatised 2,3,7,8,10-pentaoxygenated benzo[c]phenanthridine alkaloids
Miyoji Hanaoka Nobuyuki Kobayashi Ken-ichi Shimada and Chisato Mukai
pg 677; DOI:
10.1039/P19870000677
PDF
N-(alkylphenylphosphinoyl)hydroxylamines: highly selective migration of the phenyl group in the base-induced rearrangement of their O-methylsulphonyl derivatives
Martin J. P. Harger and Adrian Smith
pg 683; DOI:
10.1039/P19870000683
PDF
Tetrahydroisoquinolines. Part 3. Stereoselective synthesis of cis- and trans-1,4-disubstituted N-methyl-1,2,3,4-tetrahydroisoquinolines as their tricarbonylchromium complexes
Julian Blagg Steven J. Coote Stephen G. Davies David Middlemiss and Alan Naylor
pg 689; DOI:
10.1039/P19870000689
PDF
Reactivity of 1,2-benzisoxazole 2-oxides
A. J. Boulton Petros G. Tsoungas and Chris Tsiamis
pg 695; DOI:
10.1039/P19870000695
PDF
Lewis acid-promoted conjugate reduction of ,-unsaturated carbonyl compounds by 2-phenylbenzothiazoline (2-phenyl-2,3-dihydrobenzothiazole)
Hidenori Chikashita Makoto Miyazaki and Kazuyoshi Itoh
pg 699; DOI:
10.1039/P19870000699
PDF
The synthesis of 9,10-dimethyl-4,6,6a,7,8,9,10,10a-octahydroindolo[3,4-gh]isoquinoline, the 8,9-dimethyl-8-aza analogue of ergoline
William H. Hunter and David E. Tupper
pg 707; DOI:
10.1039/P19870000707
PDF
Gas–liquid phase-transfer catalysis: Wittig–Horner reaction in heterogeneous conditions
Enrico Angeletti Pietro Tundo and Paolo Venturello
pg 713; DOI:
10.1039/P19870000713
PDF
Addition of arylsulphonylcarbenes to benzene
Romuald Bartnik and Krystyna Wawrynko
pg 715; DOI:
10.1039/P19870000715
PDF
Synthetic routes to the piperolides, fadyenolides, epoxypiperolides, and related compounds
Andrew Pelter Redha I. H. Al-Bayati Migdad T. Ayoub Wynn Lewis Pushpa Pardasani and Rudolf Hansel
pg 717; DOI:
10.1039/P19870000717
PDF
Studies on the scope of the aza-di--methane rearrangement of ,-unsaturated imines
Diego Armesto Fernando Langa Juan-Antonio Fernandez Martin Rafael Perez-Ossorio and William M. Horspool
pg 743; DOI:
10.1039/P19870000743
PDF
Electrophilic substitution in (arene)tricarbonylchromium complexes. Part 1
Joseph L. von Rosenberg and A. Reginald Pinder
pg 747; DOI:
10.1039/P19870000747
PDF
Preparation of 7-hydroxy-2-oxoindolin-3-ylacetic acid and its [13C2], [5-n-3H], and [5-n-3H]-7-O-glucosyl analogues for use in the study of indol-3-yl-acetic acid catabolism
Paul Lewer
pg 753; DOI:
10.1039/P19870000753
PDF
Regiochemical control in the alkylation of tetrahydroindanones
Thomas V. Lee and Judy Toczek
pg 759; DOI:
10.1039/P19870000759
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Polyhalogenoheterocyclic compounds. Part 38. Reactions of fluorinated-alkenes and -cycloalkenes with difunctional nucleophiles
Andrew E. Bayliff Martin R. Bryce and Richard D. Chambers
pg 763; DOI:
10.1039/P19870000763
PDF
Carbanions derived from 2-alkylthiobenzothiazoles. A novel -lithiomethyl mercaptan synthon for mercaptomethylation
Alan R. Katritzky Jose M. Aurrecoechea and Luis M. Vazquez de Miguel
pg 769; DOI:
10.1039/P19870000769
PDF
The lithiation of 1-(phenylthiomethyl)benzimidazole and related compounds
Alan R. Katritzky Wolfgang H. Ramer and Jamshed N. Lam
pg 775; DOI:
10.1039/P19870000775
PDF
The chemistry of N-substituted benzotriazoles. Part 1.1-(Chloromethyl)benzotriazole
Alan R. Katritzky Stanislaw Rachwal Kenneth C. Caster Fatma Mahni Kam Wah Law and Olga Rubio
pg 781; DOI:
10.1039/P19870000781
PDF
The chemistry of N-substituted benzotriazoles. Part 2. Reactions of benzotriazole with aldehydes and aldehyde derivatives. 1-(-Hydroxyalkyl)-, 1-(-alkoxyalkyl)-, and 1-(-acyloxyalkyl)benzotriazoles
Alan R. Katritzky Stanislaw Rachwal and Bogumila Rachwal
pg 791; DOI:
10.1039/P19870000791
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The chemistry of benzotriazole. Part 3. The aminoalkylation of benzotriazole
Alan R. Katritzky Stanislaw Rachwal and Bogumila Rachwal
pg 799; DOI:
10.1039/P19870000799
PDF
The chemistry of N-substituted benzotriazoles. Part 4. A novel and versatile method for the mono-N-alkylation of aromatic and heteroaromatic amines
Alan R. Katritzky Stanislaw Rachwal and Bogumila Rachwal
pg 805; DOI:
10.1039/P19870000805
PDF
The chemistry of N-substituted benzotriazoles. Part 5. Reactions of benzotriazole with aldehydes and thionyl chloride—formation of (benzotriazol-1-yl)-1-chloroalkanes and bis(benzotriazolyl)alkanes
Alan R. Katritzky Wojciech Kuzmierkiewicz Bogumila Rachwal Stanislaw Rachwal and Julie Thomson
pg 811; DOI:
10.1039/P19870000811
PDF
The chemistry of N-substituted benzotriazoles. Part 6. A new synthetic route to aromatic ketones
Alan R. Katritzky and Wojciech Kuzmierkiewicz
pg 819; DOI:
10.1039/P19870000819
PDF
Stereochemistry in the Knoevenagel reaction of methyl arylsulphinylacetate and aldehydes
Rikuhei Tanikaga Naoto Konya Tadashi Tamura and Aritsune Kaji
pg 825; DOI:
10.1039/P19870000825
PDF
Synthesis and properties of methano bridged tetradehydro-[18]annulene, -[20]annulene, -[22]annulene, -[24]annulene, and the related [1,3]cyclophanpolyenediyne compounds
Jro Ojima Emiko Ejiri Tadahito Kato Mitsunobu Nakamura Shigeyasu Kuroda Shuji Hirooka and Mitsuo Shibutani
pg 831; DOI:
10.1039/P19870000831
PDF
Reagents and synthetic methods. Part 58. Synthesis of -lactams from acetic acids and imines promoted by Vilsmeier type reagents
Ana Arrieta Begoña Lecea and Claudio Palomo
pg 845; DOI:
10.1039/P19870000845
PDF
Synthesis of substituted dibenzophospholes. Part 5. Synthesis of intermediates for 4-and 6-aryl substituents
Nabeel H. Buttrus Sir John Cornforth Peter B. Hitchcock Ashok Kumar and Alan S. Stuart
pg 851; DOI:
10.1039/P19870000851
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Synthesis of substituted dibenzophospholes. Part 6. Preparation of symmetrical and non-symmetrical quaterphenyl intermediates
Sir John Cornforth Ashok Kumar and Alan S. Stuart
pg 859; DOI:
10.1039/P19870000859
PDF
Synthesis of substituted dibenzophospholes. Part 7. Regiospecific synthesis of 4,6-diaryl-3,7-dioxydibenzophospholes from 2,24,4-tetranitrobiphenyl
Sir John Cornforth and Alan D. Robertson
pg 867; DOI:
10.1039/P19870000867
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Synthesis of substituted dibenzophospholes. Part 8. Synthesis and resolution of atropisomers of a 4,6-diaryldibenzophosphole
Sir John Cornforth Lynn M. Huguenin and John R. H. Wilson
pg 871; DOI:
10.1039/P19870000871
PDF
Synthesis of 1,2-diazetidinones (aza--lactams) by photochemical ring contraction
Geoffrey Lawton Christopher J. Moody and Christopher J. Pearson
pg 877; DOI:
10.1039/P19870000877
PDF
Regioselectivity in the photochemical ring contraction of 4-diazopyrazolidine-3,5-diones to give aza--lactams
Geoffrey Lawton Christopher J. Moody Christopher J. Pearson and David J. Williams
pg 885; DOI:
10.1039/P19870000885
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Rhodium carbenoid mediated cyclisations. Synthesis of 1,2-diazetidinones (aza--lactams)
Geoffrey Lawton Christopher J. Moody and Christopher J. Pearson
pg 899; DOI:
10.1039/P19870000899
PDF
Resolution of 7,7-dimethylbicyclo[3.2.0]hept-2-en-6-one using Mortierella ramanniana and 3,20-hydroxy-steroid dehydrogenase, photochemistry of 3-hydroxy-7,7-dimethylbicyclo[3.2.0]heptan-6-ones, and the synthesis of (+)-eldanolide
Suzanne Butt H. Geoff Davies Michael J. Dawson Gordon C. Lawrence Jeff Leaver Stanley M. Roberts Michael K. Turner Basil J. Wakefield Wilfred F. Wall and John A. Winders
pg 903; DOI:
10.1039/P19870000903
PDF
Saturated heterocycles. Part 88. Synthesis of a new ring system: dipyrido[1,2-a:4,3-d]pyrimidin-11-one derivatives
Imre Huber Ferenc Fülöp György Dombi Gábor Bernáth István Hermecz and Zoltán Mészáros
pg 909; DOI:
10.1039/P19870000909
PDF
Vinyl azides in heterocyclic synthesis. Part 5. Thermal and photochemical decomposition of azidocinnamates containing ortho-cycloalkylidene substituents
Christopher J. Moody and Graham J. Warrellow
pg 913; DOI:
10.1039/P19870000913
PDF
Vinyl azides in heterocyclic synthesis. Part 6. Synthesis of isoquinolines by intramolecular aza-Wittig reaction
Deirdre M. B. Hickey A. Roderick MacKenzie Christopher J. Moody and Charles W. Rees
pg 921; DOI:
10.1039/P19870000921
PDF
Vinyl azides in heterocyclic synthesis. Part 7. Synthetic studies on the cytotoxic marine alkaloid amphimedine
Carmen V. Labarca A. Roderick MacKenzie Christopher J. Moody Charles W. Rees and Juan J. Vaquero
pg 927; DOI:
10.1039/P19870000927
PDF
Vinyl azides in heterocyclic synthesis. Part 8. Synthesis of the naturally occurring phosphodiesterase inhibitors PDE-I and PDE-II
Richard E. Bolton Christopher J. Moody Charles W. Rees and Gabriel Tojo
pg 931; DOI:
10.1039/P19870000931
PDF
Intramolecular functionalization of N-cyanamide radicals: synthesis of 1,4-and 1,5-N-cyanoepimino compounds
Reyes Carrau Rosendo Hernández Ernesto Suárez and Carmen Betancor
pg 937; DOI:
10.1039/P19870000937
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Reactions of carboxylic acid derivatives with superoxide
Alexander R. Forrester and Vemeshetti Purushotham
pg 945; DOI:
10.1039/P19870000945
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Additions and corrections
Alison M. Fraser and David J. Robins
pg 949; DOI:
10.1039/P19870000949
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Isolation and identification of the hydrolytic degradation products of ranitidine hydrochloride
Phillip A. Haywood Michael Martin-Smith Trevor J. Cholerton and Michael B. Evans
pg 951; DOI:
10.1039/P19870000951
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Reactivity of 4-amino-2-benzyl-2,3-dihydro-3-oxo-1,2,5-thiadiazole 1,1-dioxide towards amines: synthesis of potential histamine H2-receptor antagonists
Vicente J. Arán José R. Ruiz and Manfred Stud
pg 955; DOI:
10.1039/P19870000955
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N,O-heterocycles. Part 18. Regiochemistry and site selectivity of N-alkylhydroxylamine addition to 2,3-diphenylcyclopropenone
Angelo Liguori Giovanni Sindona and Nicola Uccella
pg 961; DOI:
10.1039/P19870000961
PDF
Phenylthioallyl and phenylthiovinyl phosphine oxides: synthesis of 1-phenylthiobutadienes and a three-component synthesis of ketones
J. Ian Grayson Stuart Warren and Alex T. Zaslona
pg 967; DOI:
10.1039/P19870000967
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Intramolecular 1,3-dipolar cycloaddition of alkyl azidoalkylidenemalonate and 1,3-dipolar cycloreversion of the triazoline intermediate: synthesis and reactions of an N-sulphonyl-2,4-dihydropyrrolo[3,4-b]indole
Chin-Kang Sha Kuang-Sein Chuang and Shiow-Jyi Wey
pg 977; DOI:
10.1039/P19870000977
PDF
Photochemistry of organo-halogenic molecules. Part 20. The effect of cycloalkene structure on the [2 + 2] photocycloaddition to hexafluorobenzene
Boris ket Nataa Zupani and Marko Zupan
pg 981; DOI:
10.1039/P19870000981
PDF
Synthesis and resolution of albicanic acid. Simple access to optically active drimane sesquiterpenes
Valentine Ragoussis Maria Liapis and Nikitas Ragoussis
pg 987; DOI:
10.1039/P19870000987
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1,2-Asymmetric induction in intramolecular Michael reaction. A novel and enantioselective route to (+)-Geissman lactone
Kozo Shishido Yuko Sukegawa Keiichiro Fukumoto and Tetsuji Kametani
pg 993; DOI:
10.1039/P19870000993
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A new spiro annellation reaction in the isoxazole series: applications and limits. Part 2. Reactivity of ethyl 4-nitro-3-phenylisoxazole-5-carboxylate with nitrogen binucleophiles
Rodolfo Nesi Stefano Chimichi Donatella Giomi Piero Sarti-Fantoni and Piero Tedeschi
pg 1005; DOI:
10.1039/P19870001005
PDF
Stereoselective olefin formation from the dehydration of 1-(p-alkoxyphenyl)-1,2-diphenylbutan-1-ols: application to the synthesis of tamoxifen
Raymond McCague
pg 1011; DOI:
10.1039/P19870001011
PDF
Stereoselective bifunctionalization of alkynes by means of the mercury(II) salt–iodine combination
José Barluenga José M. Martínez-Gallo Carmen Nájera and Miguel Yus
pg 1017; DOI:
10.1039/P19870001017
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Carbonylation of aryl halides and vinyl bromides mediated by tetracarbonylcobalt anion
Masahiro Miura Fumiaki Akase Masato Shinohara and Masakatsu Nomura
pg 1021; DOI:
10.1039/P19870001021
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Synthesis of pyrrolo[2,1-c][1,4]benzothiazines by annellation of 3-alkoxycarbonylmethylene-4H-1,4-benzothiazines (-enamine esters) with dimethyl acetylenedicarboxylate
Giuseppe Trapani Antonia Reho Andrea Latrofa Flaviano Morlacchi Gaetano Liso and Francesca Stasi
pg 1027; DOI:
10.1039/P19870001027
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2-Chloro-3,4-dihydroimidazole. Part 2. Synthesis of cyanines from 6-aryl-2,3-dihydro-6aH-imidazo[1,2-a]pyrido[1,2-c][1.3.5]triazin-5(6H)-ones. Crystal and molecular structure of 6-phenyl-2,3-dihydro-6aH-imidazo[1,2-a]pyrido[1,2-c][1,3,5]triazin-5(6H)-one
Franciszek Saczewski Maria Gdaniec and Krzysztof Omiaowski
pg 1033; DOI:
10.1039/P19870001033
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3-Aryl-1-tetrazol-5-yltriazenes, bench-stable arenediazonium ion synthons: synthesis of biaryls and aryl halides
Richard N. Butler Paul D. O'shea and Declan P. Shelly
pg 1039; DOI:
10.1039/P19870001039
PDF
Hard acid and soft nucleophile systems. Part 11. Hard-soft affinity inversion: dehalogenation of -halogeno ketones with aluminium chloride and a thiol
Kaoru Fuji Manabu Node Takeo Kawabata and Mayumi Fujimoto
pg 1043; DOI:
10.1039/P19870001043
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Bromination of certain aryl substituted pyrrolidines
Keith W. Blake Iain Gillies and Ronald C. Denney
pg 1049; DOI:
10.1039/P19870001049
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Enantiotopic-group differentiation. Catalytic asymmetric ring-opening of prochiral cyclic acid anhydrides with methanol, using cinchona alkaloids
Jun Hiratake Minoru Inagaki Yukio Yamamoto and Jun'ichi Oda
pg 1053; DOI:
10.1039/P19870001053
PDF
Electrophilic addition of benzeneselenenyl chloride to alkenes bearing an electron-withdrawing substituent
Akio Toshimitsu Keiji Terao and Sakae Uemura
pg 1059; DOI:
10.1039/P19870001059
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meso-Reactivity of porphyrins and related compounds. Part 9. Photo-oxygenation of octaethyloxophlorin
Raymond Bonnett and Brian D. Chaney
pg 1063; DOI:
10.1039/P19870001063
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Metal-assisted reactions: part 19. Burst kinetics in heterogeneous catalytic transfer hydrogenolysis
Robert A. W. Johnstone and Peter J. Price
pg 1069; DOI:
10.1039/P19870001069
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Oxidation of a nitronyl nitroxide by copper(II) ions: synthesis and X-ray diffraction characterization of 4,4,5,5-tetramethyl-1-oxo-2-phenyl-4,5-dihydroimidazolium perchlorate N(3)-oxide
A. Caneschi J. Laugier and P. Rey
pg 1077; DOI:
10.1039/P19870001077
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Acid-catalysed coupling reactions and conversions of isoflavone epoxides
Barend C. B. Bezuidenhoudt E. Vincent Brandt and Daneel Ferreira
pg 1081; DOI:
10.1039/P19870001081
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Application of 2H n.m.r. spectroscopy to study the incorporation of enantiomeric [2-2H]-labelled putrescines into the pyrrolizidine alkaloid retrorsine
Ellen K. Kunec and David J. Robins
pg 1089; DOI:
10.1039/P19870001089
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Carbon–carbon bond forming reactions via-phosphoryl--thio carbocations
Hiroyuki Ishibashi Tatsunori Sato Maki Irie Masae Ito and Masazumi Ikeda
pg 1095; DOI:
10.1039/P19870001095
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Alkene cyclisations of N-alkenyl--(methylsuiphinyl)acetamides and N-alkenyl--chloro--(methylthio)acetamides: novel synthesis of five-, six-, and seven-membered lactams
Hiroyuki Ishibashi Masazumi Ikeda Hiroshi Maeda Ko-ichi Ishiyama Minako Yoshida Shuji Akai and Yasumitsu Tamura
pg 1099; DOI:
10.1039/P19870001099
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Studies on conformationally restricted, disiloxane bridged analogues of the enkephalins
John S. Davies E. John Tremeer and Richard C. Treadgold
pg 1107; DOI:
10.1039/P19870001107
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Synthesis of new 2-mono- and 2,5-di-functionalized pyrrolidin-1-oxyl spin labels
Kálmán Hideg and László Lex
pg 1117; DOI:
10.1039/P19870001117
PDF
Isolation and synthesis of 1,7-dioxaspiro[5.5]undecane and 1,7-dioxaspiro[5.5]undecan-3-and -4-ols from the olive fly (Dacus oleae)
Raymond Baker and Richard H. Herbert
pg 1123; DOI:
10.1039/P19870001123
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The selective protection of the 3-ketone functions of steroids as heptafluoro-p-tolyl enol ethers
Michael Jarman and Raymond McCague
pg 1129; DOI:
10.1039/P19870001129
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Intramolecular reactions of N-nitrenes: description of the transition state geometry for addition to alkenes
Robert S. Atkinson and Michael J. Grimshire
pg 1135; DOI:
10.1039/P19870001135
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Thermal cycloaddition of N-arylmaleimides to phenols: the convenient synthesis of bicyclo[2.2.2]oct-2-en-5-one and tricyclo[3.3.0.02,8]octan-2-one derivatives from phenols
Derek Bryce-Smith Andrew Gilbert Ian S. McColl Michael G. B. Drew and Paul Yianni
pg 1147; DOI:
10.1039/P19870001147
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N-substituted N-acyl- and N-imidoyl-thioureas: preparation and conversion of N,N-disubstituted compounds into 2-(N,N-disubstituted amino)thiazol-5-yl ketones
Jocelyn C. Brindley Jennifer M. Caldwell G. Denis Meakins Simon J. Plackett and Susan J. Price
pg 1153; DOI:
10.1039/P19870001153
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peri-Substituted imidazo[1,2-a]pyridines. A new reductive elimination reaction
Charles W. Rees and David I. Smith
pg 1159; DOI:
10.1039/P19870001159
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The allyl group for protection in carbohydrate chemistry. Part 19. The coupling of allyl 2,3-di-O-methyl-4-O-(3,6-di-O-methyl--D-glucopyranosyl)--L-rhamnopyranoside to bovine serum albumin. Preparation of a diagnostic reagent for antibodies to the major glycolipid of Mycobacterium leprae(the leprosy bacillus) in human sera
Jill Gigg Roy Gigg Sheila Payne and Robert Conant
pg 1165; DOI:
10.1039/P19870001165
PDF
Synthesis of 8,9,10,11,12,13,13a,14-octahydro-7,11; 9,13-dimethanoazonino[1,2-b]isoquinolin-5(7H)-ones and some related derivatives by photocyclization reactions of 5-methylene-4-aroyl- and -acryloyl-4- azatricyclo[4.3.1.13,8]undecanes (4-azahomoadamantanes)
Shoji Eguchi Koji Asai Hisato Takeuchi and Tadashi Sasaki
pg 1171; DOI:
10.1039/P19870001171
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Stereospecific synthesis of N-protected statine and its analogues via chiral tetramic acid
Patrick Jouin Bertrand Castro and Dino Nisato
pg 1177; DOI:
10.1039/P19870001177
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Autoxidation and solvolysis products of octaethylverdohaemochrome
Setsuo Saito and Harvey A. Itano
pg 1183; DOI:
10.1039/P19870001183
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Novel semisynthetic oxo and alkyl macrolide antibacterials and related derivatives
Andrew G. Fishman Alan K. Mallams Mohindar S. Puar Randall R. Rossman and Richard L. Stephens
pg 1189; DOI:
10.1039/P19870001189
PDF
Reactions of xanthinium N(7)-ylides with olefinic dipolarophiles
Mikio Hori Tadashi Kataoka Hiroshi Shimizu Eiji Imai Yukiharu Matsumoto Masanori Kawachi Kazuyoshi Kuratani Haruo Ogura and Hiroaki Takayanagi
pg 1211; DOI:
10.1039/P19870001211
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The reactivity of silyl ethers to the Swern reagent
Carlos M. Afonso M. Teresa Barros and Christopher D. Maycock
pg 1221; DOI:
10.1039/P19870001221
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Photochemical reactions of pyridine-4-thiones and acridine-9-thiones with alkenes
Takehiko Nishio
pg 1225; DOI:
10.1039/P19870001225
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Cyclizations of terminally substituted a,c-biladiene salts to give meso-substituted porphyrins
Kevin M. Smith and Ravindra K. Pandey
pg 1229; DOI:
10.1039/P19870001229
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New approaches to the synthesis of -lactam antibiotics
John Knight and Philip J. Parsons
pg 1237; DOI:
10.1039/P19870001237
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Reactions of carbamyl (urethanyl) radicals: intramolecular aromatic additions
Patrick F. Dicks Stephen A. Glover André Goosen and Cedric W. McCleland
pg 1243; DOI:
10.1039/P19870001243
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Synthesis of 16-substituted 17-nor-13-steroids and skeletal rearrangement of 17-nor-5,13-androstane-16-carbonyl m-chlorobenzoyl peroxide
Hiroshi Suginome Yoshihiko Ohue and Kazuhiko Orito
pg 1247; DOI:
10.1039/P19870001247
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Thallium(III) nitrate-mediated efficient synthesis of 2-arylpropionic acids from 1-halogenoethyl aryl ketones
Takayoshi Yamauchi Kenji Nakao and Kyoichi Fujii
pg 1255; DOI:
10.1039/P19870001255
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Oxidation of N-acyl-pyrrolidines and -piperidines with lron(II)-hydrogen peroxide and an iron complex-molecular oxygen
Satoru Murata Masahiro Miura and Masakatsu Nomura
pg 1259; DOI:
10.1039/P19870001259
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Acid-catalysed intramolecular C-alkylation in ,-unsaturated diazomethyl ketones. Part 5. Synthesis of functionalised hydrofluorene derivatives via novel fragmentation reactions
Bijali Saha Gutta O. S. V. Satyanarayana and Usha Ranjan Ghatak
pg 1263; DOI:
10.1039/P19870001263
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Nucleoside phosphonates: part 7. Studies on the oxidation of nucleoside phosphonate esters
Per J. Garegg Tor Regberg Jacek Stawinski and Roger Strömberg
pg 1269; DOI:
10.1039/P19870001269
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The synthesis of diethyl p-tolylsulphonylethynylphosphonate and related acetylenes, and their reactions with nucleophiles, pyridinium-1-dicyanomethylides, and dienes
R. Morrin Acheson and Peter J. Ansell
pg 1275; DOI:
10.1039/P19870001275
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Synthesis and stereochemistry of 23,24-dihydrocalysterol: implications for marine sterols of a unified biosynthetic scheme involving protonated cyclopropanes
John R. Proudfoot and Carl Djerassi
pg 1283; DOI:
10.1039/P19870001283
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Synthesis and stereochemistry of ficisterol and norficisterol: biosynthetic implications
Arthur Y. L. Shu and Carl Djerassi
pg 1291; DOI:
10.1039/P19870001291
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Sterols in marine invertebrates. Part 57. Stereostructure, synthesis, and acid-catalysed isomerization of hebesterol—a biosynthetically significant cyclopropyl-containing marine sterol
Jin-Ho Cho and Carl Djerassi
pg 1307; DOI:
10.1039/P19870001307
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Formation of glycosides by epoxidation-ring closure of open-chain hydroxyenol ethers obtained from sugars
Francesco Nicotra Luigi Panza Fiamma Ronchetti Giovanni Russo and Lucio Toma
pg 1319; DOI:
10.1039/P19870001319
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Some chemical reactions of 5-vinyluracil and 2-deoxy-5-vinyluridine
A. Stanley Jones Martin J. Slater and Richard T. Walker
pg 1325; DOI:
10.1039/P19870001325
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Stereoselective total synthesis of ()-3-oxosilphinene through intramolecular Diels–Alder reaction
Masataka Ihara Akihiro Kawaguchi Hitoshi Ueda Masatoshi Chihiro Keiichiro Fukumoto and Tetsuji Kametani
pg 1331; DOI:
10.1039/P19870001331
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18-Substituted steroids. Part 12. Synthesis of aldosterone 21-sulphate, and an improved general procedure for preparing steroid sulphates
David N. Kirk and Maruthiandan S. Rajagopalan
pg 1339; DOI:
10.1039/P19870001339
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18-Substituted steroids. Part 13. Improved preparation of the metabolites of aldosterone reduced in ring A
David N. Kirk and Maruthiandan S. Rajagopalan
pg 1343; DOI:
10.1039/P19870001343
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Reaction of dimethylvinylidene carbene with methylpyrroles
Ian Birtwistle and Vernon Rogers
pg 1347; DOI:
10.1039/P19870001347
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Structure elucidation of the macrocyclic antibiotic lipiarmycin
Alberto Arnone Gianluca Nasini and Bruno Cavalleri
pg 1353; DOI:
10.1039/P19870001353
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Synthesis of ring-A and -B substituted 17-acetoxypregnan-20-one derivatives with potential activity on the digitalis receptor in cardiac muscle
John F. Templeton V. P. Sashi Kumar Ryungsoon S. Kim and Frank S. LaBella
pg 1361; DOI:
10.1039/P19870001361
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Wittig reactions with -lactam carbonyl functions. The effect of C-7 substitution on the chemistry of penicillins and clavulanic acid derivatives
Martin L. Gilpin John B. Harbridge and T. Trefor Howarth
pg 1369; DOI:
10.1039/P19870001369
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14-Methyl steroids. Part 5. Structural features influencing stereoselectivity of 14-methylation of 15-oxo-19-norsteroids: synthesis of 14-methyl-19-norprogesterone
Karl Bischofberger James R. Bull and Jan Floor
pg 1377; DOI:
10.1039/P19870001377
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Propentdyopents [5-(2-oxo-2H-pyrrol-5-ylmethylene)pyrrol-2(5H)-ones] and related compounds. Part 2. The ZE photoisomerisation of pyrromethenone systems
Raymond Bonnett Dariush Hamzetash and María Asunción Vallés
pg 1383; DOI:
10.1039/P19870001383
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Synthesis and properties of 4H-imidazoles
Michael Casey Christopher J. Moody and Charles W. Rees
pg 1389; DOI:
10.1039/P19870001389
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Vinyl azides in heterocyclic synthesis. Part 9. Synthesis of the isoquinolone alkaloid siamine by intramolecular aza-Wittig reaction
Michael Kennedy Christopher J. Moody Charles W. Rees and Juan J. Vaquero
pg 1395; DOI:
10.1039/P19870001395
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Influence of ortho methyl and isopropyl substituents on the reactivity of N-t-butyl P-arylphosphonamidic chlorides with isopropylamine and t-butylamine: steric acceleration of metaphosphonimidate formation by an elimination addition mechanism; contrasting behaviour of N,N-dimethyl P-arylphosphonamidic chlorides
Sally Freeman and Martin J. P. Harger
pg 1399; DOI:
10.1039/P19870001399
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Gas phase rearrangement reactions of 2-(arylamino)phenylaminyl radicals
J. I. G. Cadogan H. Susan Hutchison and Hamish McNab
pg 1407; DOI:
10.1039/P19870001407
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5-Thiopyranoses. Part 11. Isopropylidene acetals of 5-thio-D-glucose, 5-thio-D-allose, and 5-thio-D-altrose and some of their methyl glycosides
Najim A. L. Al-Masoudi and Neil A. Hughes
pg 1413; DOI:
10.1039/P19870001413
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Additions and corrections
Babajide I. Alo Emmanuel A. Adegoke Mamoudou Ligali-Ali E. Kayode Adesogan Leslie Crombie Raymond C. F. Jones and Christopher J. Palmer
pg 1421; DOI:
10.1039/P19870001421
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Halogenation of phenols and phenyl ethers with potassium halides in the presence of 18-crown-6 on oxidation with m-chloroperbenzoic acid
Moris Srebnik Raphael Mechoulam and Irene Yona
pg 1423; DOI:
10.1039/P19870001423
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Studies in the chemical constituents of Azadirachta indica A. Juss (meliaceae). Part 10. Isolation and structure elucidation of isonimolicinolide, the first 17-acetoxy tetranortriterpenoid and nimolicinoic acid, the first hexanortriterpenoid with an apoeuphane (apotirucallane) skeleton
Salimuzzaman Siddiqui Tariq Mahmood Shaheen Faizi and Bina S. Siddiqui
pg 1429; DOI:
10.1039/P19870001429
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Oxidative rearrangement of aryl ethyl ketones to alkyl 2-arylpropanoates by lead(IV) acetate
Takayoshi Yamauchi Kenji Nakao and Kyoichi Fujii
pg 1433; DOI:
10.1039/P19870001433
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Azoles. Part 4. Nucleophilic substitution reactions of halogenoimidazoles
Brian Iddon Nazir Khan and Bee Lan Lim
pg 1437; DOI:
10.1039/P19870001437
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Azoles. Part 5. Metal-halogen exchange reactions of polybromoimidazoles
Brian Iddon and Nazir Khan
pg 1445; DOI:
10.1039/P19870001445
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Azoles. Part 6. A convenient synthesis of polysubstituted imidazoles from 1-protected 2,4,5-tribromoimidazoles
Brian Iddon and Nazir Khan
pg 1453; DOI:
10.1039/P19870001453
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Azoles. Part 7. A convenient synthesis of thieno[2,3-d]imidazoles
Brian Iddon Nazir Khan and Bee Lan Lim
pg 1457; DOI:
10.1039/P19870001457
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Asymmetric synthesis of optically active threo- and erythro-pyrrolidinylbenzyl alcohol by the highly stereospecific arylation of (S)-proline and the subsequent highly diastereoselective reduction of the -amino ketone
Atsuhiro Ookawa and Kenso Soai
pg 1465; DOI:
10.1039/P19870001465
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Reaction of -halogeno ketones with carbonyl compounds promoted by CeI3, CeCl3–NaI, or CeCl3–SnCl2
Shin-ichi Fukuzawa Takuya Tsuruta Tatsuo Fujinami and Shizuyoshi Sakai
pg 1473; DOI:
10.1039/P19870001473
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Hydrolysis of bismetallic complexes of linalyldiphosphate and their participation in the biosynthesis of cyclic monoterpenes
Gloria Portilla M. Cecilia Rojas Evaristo Chiong and Osvaldo Cori
pg 1479; DOI:
10.1039/P19870001479
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Total synthesis and X-ray crystal structure of 13,14-didehydro-11-deoxy-11-methyl-l5-oxoprostaglandin E1
Randall S. Matthews Joel D. Oliver James F. Ward David J. Eickhoff and Larry C. Strickland
pg 1485; DOI:
10.1039/P19870001485
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Stereoselective synthesis of trans-2-aryl-3-(2-pyridyl)aziridines from an -silyl carbanion
Takeo Konakahara Masayuki Matsuki Shinji Sugimoto and Kenji Sato
pg 1489; DOI:
10.1039/P19870001489
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Lithium aluminium hydride reduction of chiral benzoylformamides derived from chiral amino alcohols
Choji Kashima Kazuo Harada and Yoshimori Omote
pg 1495; DOI:
10.1039/P19870001495
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Ketene S,N-acetals as synthetic intermediates for heterocycles. Reaction of ketene S,N-acetals with 1,4-quinones
Hiroki Takahata Akira Anazawa Keiko Moriyama and Takao Yamazaki
pg 1501; DOI:
10.1039/P19870001501
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Syntheses and properties of dicyanodimethyltetradehydro-trideca-, -pentadeca-, -heptadeca-, and -nonadeca-annulenes, and benzannelated tridecafulvene derivatives
Júro Ojima Shuichi Ishizaka Yasunao Shiraiwa Emiko Ejiri Tadahito Kato Shigeyasu Kuroda and Hideya Takeda
pg 1505; DOI:
10.1039/P19870001505
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Reaction of diazonium salts with transition metals. Part 13. Palladium-catalyzed carbonylative coupling of arenediazonium salts with organotin reagents to give aromatic ketones
Kiyoshi Kikukawa Tohru Idemoto Atsuhiko Katayama Kiyoshi Kono Fumio Wada and Tsutomu Matsuda
pg 1511; DOI:
10.1039/P19870001511
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Ruthenium(II)- and rhenium(III)-catalysed addition of tetrahalogenomethanes to alkenes and 1,-dienes. Stereoselective formation of cis-1,2-disubstituted cyclopentanes from 1,6-dienes
Ronald Grigg John Devlin Ashok Ramasubbu Ronald M. Scott and Paul Stevenson
pg 1515; DOI:
10.1039/P19870001515
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The chemistry of nitrilium salts. Part 4. Some reactions of 5-amino-4(C-cyanoformimidoyl)imidazoles obtained from nitrilium trifluoromethanesulphonate salts and diaminomaleonitrile
Brian L. Booth Ronald D. Coster and M. Fernanda J. R. P. Proença
pg 1521; DOI:
10.1039/P19870001521
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The conversion of the 2,3-O-isopropylidene derivative of 5-amino-1--D-ribofuranosylimidazole-4-carboxamide (AICA riboside) into 2,3-O-isopropylidene-isoguanosine
Colin B. Reese Yogesh S. Sanghvi and Reiko Kuroda
pg 1527; DOI:
10.1039/P19870001527
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Ring closure of ortho-blocked 4-aryl-1,2,4-triaza-1,3-dienes via 1,6-electrocyclisation followed by Diels–Alder dimerisation
Roberto Trave Luisa Garanti and Gaetano Zecchi
pg 1533; DOI:
10.1039/P19870001533
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Tandem Wittig reactions of 1,1-diphenylphosphorinanium salt
Iwao Yamamoto Tetsuya Fujimoto Kazuchika Ohta and Kei Matsuzaki
pg 1537; DOI:
10.1039/P19870001537
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Cinnolines. Part 1. Widman-Stoermer reactions of functionalised 2-phenylbut-2-enes to give cinnolinecarbaldehydes
John W. Barton and Neil D. Pearson
pg 1541; DOI:
10.1039/P19870001541
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Phosphorus-nitrogen compounds. Part 49. The synthesis and mechanism of formation of 6-chloro-5,6,7,12-tetrahydro-2,5,7,10-tetramethyldibenzo[d,g][1,3,2]-diazaphosphocine 6-oxide and 6-sulphide
Türsen Demir and Robert A. Shaw
pg 1547; DOI:
10.1039/P19870001547
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Alkoxycarbonylnitrenes as selective intramolecular CH-insertion reagents in alicyclic chemistry
Pierre C. Marais and Otto Meth-Cohn
pg 1553; DOI:
10.1039/P19870001553
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Synthesis and rearrangements of 1,1-bi(benzocyclobutylidene) and its derivatives
John W. Barton and Michael K. Shepherd
pg 1561; DOI:
10.1039/P19870001561
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Cyclization of isothiosemicarbazones. Part 7. Synthesis of N-alkenyl-1,2,4-triazoles with anti-Saytzeff orientation
Chiji Yamazaki Mitsuru Sakai Yoshiko Miyamoto and Narumi Suzuki
pg 1567; DOI:
10.1039/P19870001567
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The synthesis of aromatic leukotriene analogues; regioselective trapping of 2,4-dilithiophenylethyne
Mark Furber Richard J. K. Taylor and S. Cliff Burford
pg 1573; DOI:
10.1039/P19870001573
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Organic heterocyclothiazenes. Part 5. Cycloaddition reactions of tetrasulphur tetranitride with highly electron deficient alkynes
Peter J. Dunn and Charles W. Rees
pg 1579; DOI:
10.1039/P19870001579
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Organic heterocyclothiazenes. Part 6. Improved synthesis of trithiadiazepines from tetrasulphur tetranitride and alkynes
Peter J. Dunn and Charles W. Rees
pg 1585; DOI:
10.1039/P19870001585
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The biosynthesis of tuberin from tyrosine and glycine; observations on the stereochemistry associated with the conversion of glycine through methylenetetrahydrofolate into methenyltetrahydrofolate
Karl M. Cable Richard B. Herbert and Jonathan Mann
pg 1593; DOI:
10.1039/P19870001593
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Synthesis of some hexahydroazocino[4,3-b]indoles, a tetra- and two hexahydropyrrolo[1,2 : 1,2]pyrrolo[3,4-b]indoles, and a tetrahydropyrrolo[2,1 : 5,1]imidazo[3,4-a]indole. Crystal structure determination of 1,2,3,4-tetrahydro-2-phenoxycarbonyl-7-phenylsulphonylazocino[4,3-b]indol-6 (5H)-one
Jonathan D. Street Martin Harris David I. Bishop Frank Heatley Roy L. Beddoes Owen S. Mills and John A. Joule
pg 1599; DOI:
10.1039/P19870001599
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Production of (R)-1-(1,3-dithian-2-yl)propan-2-ol by microbial reduction
Rosanna Bernardi Rosanna Cardillo Dario Ghiringhelli and Orso Vajna de Pava
pg 1607; DOI:
10.1039/P19870001607
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Regioselective ring-opening and dimerisation of methyl 3,3-dimethylcyclopropenecarboxylate
Mark S. Baird Helmi H. Hussain and William Clegg
pg 1609; DOI:
10.1039/P19870001609
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Preparation of chiral lactone from laevoglucosan; a key intermediate for synthesis of the spiroacetal moieties of the avermectins and milbemycins
Raymond Baker R. Hugh O. Boyes D. Mark P. Broom Mary J. O'Mahony and Christopher J. Swain
pg 1613; DOI:
10.1039/P19870001613
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Total synthesis of (+)-milbemycin (3)
Raymond Baker Mary J. O'Mahony and Christopher J. Swain
pg 1623; DOI:
10.1039/P19870001623
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Ketene. Part 26. The reactions of 3,4-dihydroisoquinoline N-oxide with ketenes, and an attempted synthesis of 3,4-dihydro-3,3-dimethylquinoline N-oxide
Andrew R. Evans Russell Martin Giles A. Taylor and C. H. Maurice Yap
pg 1635; DOI:
10.1039/P19870001635
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Configuration of 1,10-epoxyguaianolides: stereochemistry of 1,10-epoxy-8-hydroxyachillin
Isidro G. Collado Francisco A. Macías Guillermo M. Massanet and Francisco R. Luis
pg 1641; DOI:
10.1039/P19870001641
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Ribonucleoside cyclic 3,5-phosphoramidates: synthesis, stereochemistry, and conversion into ribonucleoside cyclic 3,5-phosphorothioates and -[18O]phosphates
Janina Baraniak and Wojciech J. Stec
pg 1645; DOI:
10.1039/P19870001645
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Thromboxane A2 analogues from 8-oxabicyclo[3.2.1]oct-6-en-3-ones
Kevin G. Bowers John Mann E. Brian Walsh and Oliver W. Howarth
pg 1657; DOI:
10.1039/P19870001657
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Synthetic studies relevant to biosynthetic research on vitamin B12. Part 4. Development of the photochemical route to isobacteriochlorins
Peter J. Harrison Zhi-Chu Sheng Christopher J. R. Fookes and Alan R. Battersby
pg 1667; DOI:
10.1039/P19870001667
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Synthetic studies relevant to biosynthetic research on vitamin B12. Part 5. Synthesis of (RS)-ring-B imide
Alan R. Battersby and Steven W. Westwood
pg 1679; DOI:
10.1039/P19870001679
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Biosynthesis of porphyrins and related, macrocycles. Part 28. Development of a pulse labelling method to determine the C-methylation sequence for vitamin B12
Horst C. Uzar Alan R. Battersby T. Adrian Carpenter and Finian J. Leeper
pg 1689; DOI:
10.1039/P19870001689
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Specific Ag+ ion binding and transport properties of tripod type open-chain cryptands
Hiroshi Tsukube Kentaro Takagi Tatsuo Higashiyama Tadashi Iwachido and Naomi Hayama
pg 1697; DOI:
10.1039/P19870001697
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Aspidospermidose: a new dihydroindole alkaloid from the leaves of Rhazya stricta

pg 1701; DOI:
10.1039/P19870001701
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Synthesis of condensed tannins. Part 18. Stilbenes as potent nucleophiles in regio- and stereo-specific condensations: novel guibourtinidol-stilbenes from Guibourtia coleosperma
Jan P. Steynberg Daneel Ferreira and David G. Roux
pg 1705; DOI:
10.1039/P19870001705
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Synthesis of (25R)-[26-2H1]cholesterol and 1H n.m.r. and h.p.l.c. resolution of (25R)- and (25S)-26-hydroxycholesterol
Atsuko Uomori Shujiro Seo Tomohiro Sato Yohko Yoshimura and Ken'ichi Takeda
pg 1713; DOI:
10.1039/P19870001713
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Stereocontrolled construction of octahydroquinolizines, octahydroindolizines, hexahydrobenzo[a]quinolizines, and an octahydroindolo[2,3-a]quinolizine by an intramolecular double Michael reaction: synthesis of ()epilupinine
Masataka Ihara Tomoko Kirihara Akihiro Kawaguchi Mayumi Tsuruta Keiichiro Fukumoto and Tetsuji Kametani
pg 1719; DOI:
10.1039/P19870001719
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A novel stereoselective access to des-A B-aromatic corticosteroids via intramolecular cycloaddition reaction—potential intermediates for the synthesis of corticosteroids
Hideo Nemoto Mitsuo Nagai Yuriko Abe Mari Moizumi Keiichiro Fukumoto and Tetsuji Kametani
pg 1727; DOI:
10.1039/P19870001727
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Studies on fungal products. Part 10. Isolation and structures of novel bicoumarins, desertorins A, B, and C, from Emericella desertorum
Koohei Nozawa Hideyuki Seyea Shoichi Nakajima Shun-ichi Udagawa and Ken-ichi Kawai
pg 1735; DOI:
10.1039/P19870001735
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The preparation of 2,3,3a,4,5,6-hexahydro-8-methoxy-1H-phenalene
H. Maskill
pg 1739; DOI:
10.1039/P19870001739
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Biohydrogenation of unsaturated compounds by Saccharomyces cerevisiae. Part 1. Stereochemical aspects of the reaction and preparation of useful bifunctional chiral synthons
Patrizia Ferraboschi Paride Grisenti Rosangela Casati Alberto Fiecchi and Enzo Santaniello
pg 1743; DOI:
10.1039/P19870001743
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Biohydrogenation of unsaturated compounds by Saccharomyces cerevisiae. Part 2: (S)-(–)-Ethyl 4-hydroxy-3-methylbutanoate as a chiral synthon for the preparation of (25S)-26-hydroxycholesterol
Patrizia Ferraboschi Alberto Fiecchi Paride Grisenti and Enzo Santaniello
pg 1749; DOI:
10.1039/P19870001749
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Selective ortho-alkylation of phenols with sulphoxides via[2,3]sigmatropic rearrangement: synthesis of coumarins
Kikumasa Sato Seiichi Inoue Kimio Ozawa Tohru Kobayashi Tomomi Ota and Michiko Tazaki
pg 1753; DOI:
10.1039/P19870001753
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The allyl group for protection in carbohydrate chemistry. Part 20. Synthesis of 1L-1-O-methyl-myo-inositol [(+)-bornesitol] by resolution of ()-1,2,4-tri-O-benzyl-myo-inositol
Jill Gigg Roy Gigg Sheila Payne and Robert Conant
pg 1757; DOI:
10.1039/P19870001757
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X-Ray structural studies of stereoisomeric bi(14H-dibenzo[4,5:6,7][1,3]diazepino[2,1-a]isoindol-14-ylidene)s obtained from the reaction of 2,2-diaminobiphenyl with o-phthalaldehyde
D. Muriel Hall Hwang Huaun-Yong Joan M. Insole and Nigel P. C. Walker
pg 1763; DOI:
10.1039/P19870001763
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Regiospecific arylation of 1,4-benzoquinone cyanohydrin phosphate: synthesis of 3-aryl-4-hydroxybenzonitriles
Takushi Kurihara Shinya Harusawa Jun-Ichi Hirai and Ryuji Yoneda
pg 1771; DOI:
10.1039/P19870001771
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Photochemical synthesis of bithienyl derivatives
Maurizio D'Auria Antonella De Mico Franco D'Onofrio and Giovanni Piancatelli
pg 1777; DOI:
10.1039/P19870001777
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Hypervalent iodine oxidation of silyl enol ethers. A direct route to -hydroxy ketones
Robert M. Moriarty Michael P. Duncan and Om Prakash
pg 1781; DOI:
10.1039/P19870001781
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Synthesis of (2R,3S,4R)-3,4-dihydroxyproline from D-ribonolactone; an approach to the synthesis of polyfunctionalised D-amino acids from sugar lactones. X-Ray molecular structures of 2-azido-3,4-O-(R)-benzylidene-2-deoxy-D-ribono-1,5-lactone, 2-azido-2-deoxy-D-ribono-1,4-lactone, and (2R,3S,3R)-3,4-dihydroxyproline
Peter D. Baird Jonathan C. Dho George W. J. Fleet Josephine M. Peach Keith Prout and Paul W. Smith
pg 1785; DOI:
10.1039/P19870001785
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Synthesis of some tetrahydrosantonin derivatives with functionalised angular substituents based on remote oxidation
Masataka Watanabe and Akira Yoshikoshi
pg 1793; DOI:
10.1039/P19870001793
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Synthesis of enantiomerically pure 2,5-disubstituted tetrahydrofurans using readily prepared (2S)-1-phenylsulphonylalkan-2-ols
Rikuhei Tanikaga Ken Hosoya and Aritsune Kaji
pg 1799; DOI:
10.1039/P19870001799
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The diastereoselective functionalisation of arene tricarbonylchromium complexes containing a benzylic heteroatom substituent
Julian Blagg Stephen G. Davies Craig L. Goodfellow and Kevin H. Sutton
pg 1805; DOI:
10.1039/P19870001805
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New methods for probing the chirality of 18O-labelled phosphinic acids
Paul B. Kay and Stuart Trippett
pg 1813; DOI:
10.1039/P19870001813
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Photolytic rearrangement of metronidazole to N-(2-hydroxyethyl)-5-methyl-1,2,4-oxadiazole-3-carboxamide. Crystal structure of its 4-nitrobenzoate derivative
Brian J. Wilkins Graeme J. Gainsford and Douglas E. Moore
pg 1817; DOI:
10.1039/P19870001817
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A revised structure for dehydrotectol and tecomaquinone I
Rajinda N. Khanna Pavan K. Sharma and Ronald H. Thomson
pg 1821; DOI:
10.1039/P19870001821
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The synthesis of heteroaromatic prostacyclin analogues via keto alkyne cyclisation
Stuart Cook Douglas Henderson Kevan A. Richardson Richard J. K. Taylor John Saunders and Philip G. Strange
pg 1825; DOI:
10.1039/P19870001825
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Photosensitized oxidation of furans. Part 12. Solvent effects in thermal rearrangement of the 2,5-peroxides of 2,5-unsubstituted furans
M. Liliana Graziano M. Rosaria Iesce Angela Cinotti and Rachele Scarpati
pg 1833; DOI:
10.1039/P19870001833
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Preparation of stable 1,4-dihydropyrazines
Jean-Louis Fourrey Josiane Beauhaire and Chun Wei Yuan
pg 1841; DOI:
10.1039/P19870001841
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Studies on amino acid derivatives. Part 7. General method for the synthesis of penam and cepham and their substituted derivatives
Takuo Chiba Jun-ichi Sakaki Takumi Takahashi Kumi Aoki Akiko Kamiyama Chikara Kaneko and Masayuki Sato
pg 1845; DOI:
10.1039/P19870001845
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Synthesis of 6,7-dihydro-5H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazines by a C–C ring cyclization under mild conditions
Pedro Molina Mateo Alajarín Ma. Jesús Pérez de Veg Ma. de la Concepción Foces-Foces Felix Hernández Cano Rosa Ma. Claramunt and José Elguero
pg 1853; DOI:
10.1039/P19870001853
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Chlorous acid oxidation of trifluoromethylphenols: cyclopentenolones by benzilic acid ring contraction
Jean-Claude Blazejewski Régine Dorme and Claude Wakselman
pg 1861; DOI:
10.1039/P19870001861
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Triazolopyridines. Part 7. Preparation of bromo-triazolopyridines and -triazoloisoquinolines
Belen Abarca Rafael Ballesteros Fatemeh Mojarred Gurnos Jones and Deborah J. Mouat
pg 1865; DOI:
10.1039/P19870001865
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In vitro production and biosynthesis of fomajorin D and S by Fomes annosus(Fr.) Cooke
Dervilla M. X. Donnelly Joseph O'Reilly Judith Polonsky and M. Helen Sheridan
pg 1869; DOI:
10.1039/P19870001869
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Corrigendum
George Burton and Frank P. Harrington
pg 1873; DOI:
10.1039/P19870001873
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Condensed tannins. Base-catalysed reactions of polymeric procyanidins with phloroglucinol: intramolecular rearrangements
Peter E. Laks Richard W. Hemingway and Anthony H. Conner
pg 1875; DOI:
10.1039/P19870001875
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Horner-Wittig reactions of -aminoalkyl- and -N-acylaminoalkyldiphenylphosphine oxides: synthesis of N-allyl amines and amides and 5-diphenylphosphinoyl-2-phenyl-5,6-dihydro-4H-1,3-oxazines
David Cavalla William B. Cruse and Stuart Warren
pg 1883; DOI:
10.1039/P19870001883
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Synthesis of benzocarbacephem and benzocarbapenem derivatives by copper-promoted intramolecular aromatic substitution
Roger Joyeau Lal D. S. Yadav and Michel Wakselman
pg 1899; DOI:
10.1039/P19870001899
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Asymmetric conjugate addition to unsaturated chiral amido alcohols using Grignard reagents co-ordinated with tertiary amines or DBU. Preparation of optically active 3-substituted carboxylic acids and (S)-(–)-citronellol
Kenso Soai Hideaki Machida and Noriko Yokota
pg 1909; DOI:
10.1039/P19870001909
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Renin substrates. Part 2. Rapid solid phase synthesis of the ratine sequence tetradecapeptide using BOP reagent
Dung Le-Nguyen Annie Heitz and Bertrand Castro
pg 1915; DOI:
10.1039/P19870001915
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The formation of complexes between aza derivatives of crown ethers and primary alkylammonium salts. Part 9. Bicyclic derivatives of diaza crown ethers
Andrew B. Kyte Ken A. Owens Ian O. Sutherland and Roger F. Newton
pg 1921; DOI:
10.1039/P19870001921
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Regioselective Diels–Alder reactions. The nitro group as a regiochemical control element
Noboru Ono Hideyoshi Miyake Akio Kamimura and Aritsune Kaji
pg 1929; DOI:
10.1039/P19870001929
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Photochemical reactions of nitrile compounds. Part 2. Photochemistry of an ,-unsaturated ,-epoxy nitrile and an ,-cyclopropyl nitrile
Keitaro Ishii Masao Abe and Masanori Sakamoto
pg 1937; DOI:
10.1039/P19870001937
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Polarised ketene dithioacetals. Part 50. Reactions of -aroyl--bromoketene dithioacetals with hydrazine hydrate: formation of rearranged pyrazoles
Gurdeep Singh Hiriyakkanavar Ila and Hiriyakkanavar Junjappa
pg 1945; DOI:
10.1039/P19870001945
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Usefulness of poly(ethylene glycol) in synthetic reactions. Part 10. Deamination of arylamines via dediazoniation by tin–hydrochloric acid in poly(ethylene glycol)–methylene dichloride
Nobutaka Suzuki Terukazu Azuma Koichi Watanabe Tateo Nomoto Yasuji Izawa and Ahideo Tomioka
pg 1951; DOI:
10.1039/P19870001951
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An unusual C-7 ortho ester from 6-epi-gibberellin A13. X-Ray molecular structure of gibberellene C-7 ortho ester
Braulio M. Fraga Isidro González-Collado Melchor G. Hernández Fernando G. Tellado and Aurea A. Perales
pg 1955; DOI:
10.1039/P19870001955
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Pyrrole studies. Part 35. Aerial oxidation of 4-substituted 3-amino-2,5-dimethylpyrroles. An X-ray crystallographic and spectroscopic study of the oxidation products
Girolamo Cirrincione Gaetano Dattolo Anna Maria Almerico Enrico Aiello R. Alan Jones Helen M. Dawes and Michael B. Hursthouse
pg 1959; DOI:
10.1039/P19870001959
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New triterpenoid pentasaccharides from Androsace saxifragifolia
Bikas C. Pal and Shashi B. Mahato
pg 1963; DOI:
10.1039/P19870001963
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Participation of ambident neighbouring groups in hypobromous acid addition to some steroidal olefins. Competition of electronic and stereoelectronic effects
Pavel Koovský and Irena Stieborová
pg 1969; DOI:
10.1039/P19870001969
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Stereochemistry of the tetrahydroisopimaric acids: X-ray structure of methyl 8-isopimaran-18-oate
Duane F. Zinkel Roger C. Pettersen Tuli Haromy and Muttaiya Sundaralingam
pg 1975; DOI:
10.1039/P19870001975
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Reaction of mesoionic thiazol-4-ones with azodicarbonyl dipolarophiles. Cleavage modes of the bi- and tri-cyclic adducts
Tuvia Sheradsky and Norbert Itzhak
pg 1979; DOI:
10.1039/P19870001979
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Neighbouring group participation in the reduction of the diterpenoid fujenal
Mark K. Baynham Julia M. Dickinson James R. Hanson and Peter B. Hitchcock
pg 1987; DOI:
10.1039/P19870001987
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The stereochemistry of some reactions at C-16 in gibberellins; an X-ray crystallographic study of the methyl esters of gibberellin A2 and gibberellin A9 hydrochloride
Karima M. Abouamer James R. Hanson and Peter B. Hitchcock
pg 1991; DOI:
10.1039/P19870001991
PDF
Studies on chromone derivatives. Novel 1,3 dipolar cycloadditions of 4-oxo-1-benzopyran-3-carbaldehyde imines and imine oxides
Arpan K. Baruah Dipak Prajapati and Jagir S. Sandhu
pg 1995; DOI:
10.1039/P19870001995
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Photosensitised oxidation of model unsaturated lipid systems: (4Z,7Z)-undeca-4,7-diene and (4Z)-undec-4-en-7-yne
Howard A. J. Carless and Richard J. Batten
pg 1999; DOI:
10.1039/P19870001999
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Studies related to penicillins. Part 23. Preparation of the N-phenylacetyl and N-triphenylmethyl derivatives of (3R,4R)-3-amino-4-t-butylthioazetidin-2-one
David F. Corbett Arun C. Kaura Christopher D. Maycock and Richard J. Stoodley
pg 2009; DOI:
10.1039/P19870002009
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The structure and synthesis of nepenthone-A, a naphthoquinone from Nepenthes rafflesiana
Mark A. Rizzacasa and Melvyn V. Sargent
pg 2017; DOI:
10.1039/P19870002017
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Reactions of tertiary allylamines with dimethyl acetylenedicarboxylate
Kamal A. Kandeel and John M. Vernon
pg 2023; DOI:
10.1039/P19870002023
PDF
Biosynthesis of porphyrins and related macrocycles. Part 29. Synthesis and chemistry of 2,2-disubstituted 2H-pyrroles (pyrrolenines)
Alan R. Battersby Mark G. Baker Hugo A. Broadbent Christopher J. R. Fookes and Finian J. Leeper
pg 2027; DOI:
10.1039/P19870002027
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Trifluoromethanesulphonic acid as a catalyst for the ethylation of benzene
Brian L. Booth Mohammed Al-Kinany and Khosrow Laali
pg 2049; DOI:
10.1039/P19870002049
PDF
The reaction of diols with triphenylphosphine and di-isopropyl azodicarboxylate. Part 2. Formation of cyclic phosphoranes from 1,5–1,12-diols
Mark von Itzstein and Ian D. Jenkins
pg 2057; DOI:
10.1039/P19870002057
PDF
5-Thiopyranoses. Part 12. Sulphur participation in displacement reactions of sulphonate esters of 5-thio-D-allose, 5-thio-D-altrose, and 5-thio-D-glucose derivatives
Najim A. L. Al-Masoudi and Neil A. Hughes
pg 2061; DOI:
10.1039/P19870002061
PDF
Pyrrolizidine alkaloid analogues. Synthesis of 10-membered macrocyclic diesters of ()-synthanecine A. X-Ray molecular structure of ()-6,7-O,O-(succinyl)synthanecine A
Robert H. Barbour Andrew A. Freer and David J. Robins
pg 2069; DOI:
10.1039/P19870002069
PDF
On the formation and nitrogen nuclear magnetic resonance spectra of some nitrimines (pernitroso–ketones), and the mechanism of oxime cleavage by nitrous acid
Spiros Adamopoulos A. J. Boulton Rahim Tadayoni and Graham A. Webb
pg 2073; DOI:
10.1039/P19870002073
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Total synthesis of heptacyclic Aspidosperma alkaloids. Part 1. Preliminary experiments
John W. Blowers James P. Brennan and J. Edwin Saxton
pg 2079; DOI:
10.1039/P19870002079
PDF
Reactions of polyfluoro-arenols and -heteroarenols with activated dimethyl sulphoxide. Facile [2,3]-sigmatropic rearrangement reactions giving de-aromatised products
Gerald M. Brooke and J. A. K. Jamie Ferguson
pg 2091; DOI:
10.1039/P19870002091
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Studies on fungal products. Part 13. Isolation and structures of dithiosilvatin and silvathione, novel dioxopiperazine derivatives from Aspergillus silvaticus
Nobuo Kawahara Koohei Nozawa Shoichi Nakajima and Ken-ichi Kawai
pg 2099; DOI:
10.1039/P19870002099
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Structure elucidation of the glycopeptide antibiotic complex A40926
Jonathan P. Waltho Dudley H. Williams Enrico Selva and Pietro Ferrari
pg 2103; DOI:
10.1039/P19870002103
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Corrigenda
H. T. Andrew Cheung Thomas R. Watson S. Mark Lee Michael M. McChesney James N. Seiber Asit K. Chakraborti Shaikh Khairul Alam Prabir C. Chakraborti Rupak Dasgupta Jyotirmoy Chakravarty Usha Ranjan Ghatak Apurba Kabiraj Sundar Gopal Biswas Peter J. Dunn Charles W. Rees Mark S. Baird Helmi H. Hussain and William Clegg
pg 2109; DOI:
10.1039/P19870002109
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Synthesis of thiogibberellins: X-ray molecular and crystal structure of 19,10-thio-3-epigibberellin A1
Angelika Schierhorn Günter Adam Leo Kutschabsky and Peter Leibnitz
pg 2111; DOI:
10.1039/P19870002111
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Trifluoromethanethiolate ion. Part 2. Nucleophilic substitution in pentafluoropyridine. Synthesis and characteristics of trifluoromethylthio and trifluoromethylsulphonyl derivatives
Wojciech Dmowski and Alois Haas
pg 2119; DOI:
10.1039/P19870002119
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Ring opening of 2H-pyrans promoted by organometallic reagents. Synthesis of dienic alcohols
Angel Alberola Celia Andrés Alfonso González Ortega Rafael Pedrosa and Martina Vicente
pg 2125; DOI:
10.1039/P19870002125
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The synthesis of 3-(4-aminotetrafluorophenyl)-3-ethylpiperidine-2,6-dione; a fluorinated derivative of aminoglutethimide
Raymond G. Plevey and Paul Sampson
pg 2129; DOI:
10.1039/P19870002129
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Reaction of (1S,6S)-1,7,7-trimethyl-2,3-dimethylene-trans-bicyclo[4.4.0]decane with thallium(III) acetate; a new route to (–)-warburganal and (+)-euryfuran
Tatsuhiko Nakano María Aracelis Maillo and Anibal Rojas
pg 2137; DOI:
10.1039/P19870002137
PDF
Reaction of 5-trifluoromethyl-2-deoxyuridine and 1-methyl-5-trifluoromethyluracil with methoxyamine: model studies for the interaction between thymidylate synthetase and 5-trifluoromethyl-2-deoxyuridine 5-phosphate
Yusuke Wataya Yumi Sonobe Mitsuaki Maeda Ziro Yamaizumi Misako Aida and Daniel V. Santi
pg 2141; DOI:
10.1039/P19870002141
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Rearrangement of some allylic sulphinate esters to allylic sulphones. Ion-pair and sigmatropic shift mechanisms
Derek J. Knight Gordon H. Whitham and Jonathan G. Williams
pg 2149; DOI:
10.1039/P19870002149
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2-Bromo-3-methoxycyclohex-2-enone, a new reagent for the -arylation of lactams
Robin G. Shepherd and Alan C. White
pg 2153; DOI:
10.1039/P19870002153
PDF
Continuous conversion of alcohols into alkyl halides by gas–liquid phase-transfer catalysis (G.L.–P.T.C.)
Pietro Tundo Paolo Venturello and Enrico Angeletti
pg 2157; DOI:
10.1039/P19870002157
PDF
Alkylation reactions of ethyl malonate, ethyl acetoacetate, and acetylacetone by gas–liquid phase-transfer catalysis (G.L.–P.T.C.)
Pietro Tundo Paolo Venturello and Enrico Angeletti
pg 2159; DOI:
10.1039/P19870002159
PDF
Triphenylmethyl phenylcyanomethylenenitronate: formation and thermolysis
Joseph H. Boyer Thankiavelu Manimaran and Vayalakkavoor T. Ramakrishnan
pg 2163; DOI:
10.1039/P19870002163
PDF
A directed aldol approach to (+)-milbemycin 3
Philip J. Kocieski Stephen D. A. Street Clive Yeates and Simon F. Campbell
pg 2171; DOI:
10.1039/P19870002171
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The 3,4-dihydro-2H-pyran approach to (+)-milbemycin 3. Part 1. An alternative synthesis of (2S,4S,6R,8R,9S)-2-formylmethyl-4-(dimethyl-t-butylsilyloxy)-8,9-dimethyl-1,7-dioxaspiro[5.5]undecane
Philip J. Kocieski Clive Yeates Stephen D. A. Street and Simon F. Campbell
pg 2183; DOI:
10.1039/P19870002183
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The 3,4-dihydro-2H-pyran approach to (+)-milbemycin 3. Part 2. An improved synthesis of (2R,4S,6S,8R,9S)-2-[(5R)-(2E)-3-methyl-5-formyl-hex-2-en-1-yl]-8,9-dimethyl-4-(dimethyl-t-butylsilyloxy)-1,7-dioxaspiro[5.5]undecane
Philip J. Kocieski Stephen D. A. Street Clive Yeates and Simon F. Cambell
pg 2189; DOI:
10.1039/P19870002189
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Pyrrolizidine alkaloids. Stereochemistry of the enzymic processes involved in the biosynthesis of rosmarinecine
Henry A. Kelly and David J. Robins
pg 2195; DOI:
10.1039/P19870002195
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Chemistry of novel compounds with multifunctional carbon structure. Part 2. The first example of optically active multifunctional carbon compounds
Yoshio Takeuchi Masahiro Asahina Kazuhiro Nagata and Toru Koizumi
pg 2203; DOI:
10.1039/P19870002203
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Synthesis of 2,3,5-trihydroxyphenylprop-1-ene and its 4-chloro-, 6-chloro-, and 4,6-dichloro- derivatives
Robert A. Hill Graham S. Macaulay and William S. MacLachlan
pg 2209; DOI:
10.1039/P19870002209
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Structural studies on bio-active compounds. Part 5. Synthesis and properties of 2,4-diaminopyrimidine dihydrofolate reductase inhibitors bearing lipophilic azido groups
Edward A. Bliss Roger J. Griffin and Malcolm F. G. Stevens
pg 2217; DOI:
10.1039/P19870002217
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Structural studies on bio-active compounds. Part 6. Determination of the sites of protonation on three 2,4-diaminopyrimidines of pharmaceutical importance by proton-coupled 13C and 1H nuclear magnetic resonance spectroscopy
Michael D. Threadgill Roger J. Griffin Malcolm F. G. Stevens and Sang K. Wong
pg 2229; DOI:
10.1039/P19870002229
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Reaction of azoles with ethyl bromopyruvate oxime: alkylation by substitution and by elimination–addition
Thomas L. Gilchrist Wayne Stretch and Ewan J. T. Chrystal
pg 2235; DOI:
10.1039/P19870002235
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11C-labelling of substance P. Preparation of a homocysteine-containing precursor and its subsequent application in the synthesis of the labelled neuropeptide
Henry M. Franzén Ulf Ragnarsson Kjell Någren and Bengt Långström
pg 2241; DOI:
10.1039/P19870002241
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Synthesis of sequential polydepsipeptides involving depsipeptide formation by the 2-nitrophenylsulphenyl N-carboxy -amino acid anhydride (Nps–NCA) method
Ryoichi Katakai
pg 2249; DOI:
10.1039/P19870002249
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Metabolites of Aspergillus ustus. Part 4. Stable-isotope labelling studies on the biosynthesis of the austalides
Amelia E. de Jesus R. Marthinus Horak Pieter S. Steyn and Robert Vleggaar
pg 2253; DOI:
10.1039/P19870002253
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A regiocontrolled synthesis of allylstannanes
Ian Fleming and Michael Rowley
pg 2259; DOI:
10.1039/P19870002259
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The Fischer indolisation of cyclopropyl phenyl ketone and cyclobutyl phenyl ketone phenylhydrazones
Brian Robinson Munir I. Khan and Mark J. Shaw
pg 2265; DOI:
10.1039/P19870002265
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Synthesis of allenylsilanes from propargyl carbamates
Ian Fleming Ken Takaki and Andrew P. Thomas
pg 2269; DOI:
10.1039/P19870002269
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XY–ZH systems as potential 1,3-dipoles. Part 7. Stereochemistry of the cycloaddition of imines of -amino acid esters to fumarate and maleate esters
Ronald Grigg James Kemp and William J. Warnock
pg 2275; DOI:
10.1039/P19870002275
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XY–ZH Systems as potential 1,3-dipoles. Part 8. Pyrrolidines and 5-pyrrolines (3,7-diazabicyclo[3.3.0]octenes) from the reaction of imines of -amino acids and their esters with cyclic dipolarophiles. Mechanism of racemisation of -amino acids and their esters in the presence of aldehydes
Kitti Amornraksa Ronald Grigg H. Q. Nimal Gunaratne James Kemp and Visuvanathar Sridharan
pg 2285; DOI:
10.1039/P19870002285
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New syntheses of calixarene-p-sulphonates and p-nitrocalixarenes
Seiji Shinkai Koji Araki Takayuki Tsubaki Takashi Arimura and Osamu Manabe
pg 2297; DOI:
10.1039/P19870002297
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A new flexible synthesis of (R,S)-mevalonolactone
Patrizia Ferraboschi Renato Canevotti Paride Grisenti and Enzo Santaniello
pg 2301; DOI:
10.1039/P19870002301
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Structural features and crystallographic examination of 5-acetyl- and 5-trifluoroacetyl-2-(N,N-disubstituted amino)thiazoles
(Miss) Jennifer M. Caldwell G. Denis Meakins Richard H. Jones Timothy R. Kidd and Keith Prout
pg 2305; DOI:
10.1039/P19870002305
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A study of three reactions leading to isomeric 2-(N,N-disubstituted amino)thiazol-5-yl ketones
Richard A. Funnell G. Denis Meakins (Mrs). Josephine M. Peach and (Miss) Susan J. Price
pg 2311; DOI:
10.1039/P19870002311
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Synthesis of asymmetrically substituted aminohalogenobenzimidazoles
Maria-Jose Camarasa Paul L. Coe A. Stanley Jones and Richard T. Walker
pg 2317; DOI:
10.1039/P19870002317
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The synthesis of some thiophenophanes and attempted cyclisations to polycyclic thiophenium salts
R. Morrin Acheson and Gary C. M. Lee
pg 2321; DOI:
10.1039/P19870002321
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Selectivity and charge transfer in photoreactions of donor-acceptor systems. Part 10. meta Photocycloadditions of m-bis(trifluoromethyl)benzene and trifluoromethyl benzonitriles to olefins
Gabi Weber Jan Runsink and Jochen Mattay
pg 2333; DOI:
10.1039/P19870002333
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Nitrile sulphides. Part 7. Synthesis of [1]benzopyrano[4,3-c]isothiazoles and isothiazolo[4,3-c]quinolines
Peter A. Brownsort and R. Michael Paton
pg 2339; DOI:
10.1039/P19870002339
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Synthesis of condensed tannins. Part 19. Phenol oxidative coupling of (+)-catechin and (+)-mesquitol. Conformation of bis-(+)-catechins
Desmond A. Young Esmé Young David G. Roux E. Vincent Brandt and Daneel Ferreira
pg 2345; DOI:
10.1039/P19870002345
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Synthesis of condensed tannins. Part 20. Cycloconformations and conformational stability among derivatives of angular tetraflavanoid profisetinidins
Edward V. Brandt Desmond A. Young Daneel Ferreira and David G. Roux
pg 2353; DOI:
10.1039/P19870002353
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Total synthesis of analogues of the -lactam antibiotics. Part 3. 2-Ethoxycarbonyl derivatives of carbapen-1-em-3-exo-carboxylates and carbapenam-3-exo-carboxylates
Rajiv Sharma Richard J. Stoodley and Andrew Whiting
pg 2361; DOI:
10.1039/P19870002361
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A new route to chiral hydroxypyrrolidines from D-erythrose via intramolecular 1,3-cycloaddition
J. Grant Buchanan Alan R. Edgar and Brian D. Hewitt
pg 2371; DOI:
10.1039/P19870002371
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Enantiospecific synthesis of (+)-retronecine, (+)-crotonecine, and related alkaloids
J. Grant Buchanan Veerappa B. Jigajinni Gurdial Singh and Richard H. Wightman
pg 2377; DOI:
10.1039/P19870002377
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Synthesis of bipyridyl-, viologen-, and quinone-bridged porphyrins
Philip Leighton and Jeremy K. M. Sanders
pg 2385; DOI:
10.1039/P19870002385
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Synthesis and electrochemical properties of some metallated and peripherally substituted porphyrin co-facial dimers
James A. Cowan and Jeremy K. M. Sanders
pg 2395; DOI:
10.1039/P19870002395
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Structural elucidation of new diterpenoids isolated from Rabdosia umbrosa var. leucantha f. Kameba
Yoshio Takeda Teruyoshi Ichihara Yoshihisa Takaishi Tetsuro Fujita Tetsuro Shingu and Genziro Kusano
pg 2403; DOI:
10.1039/P19870002403
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The allyl group for protection in carbohydrate chemistry. Part 21. ()-1,2 : 5.6- and ()-1,2 : 3,4-di-O-isopropylidene-myo-inositol. The unusual behaviour of crystals of ()-3,4-di-O-acetyl-1,2,5,6-tetra-O-benzyl-myo-inositol on heating and cooling: a thermosalient solid
Jill Gigg Roy Gigg Sheila Payne and Robert Conant.
pg 2411; DOI:
10.1039/P19870002411
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Basic intramolecular acylation. Synthesis of 2-aryl-1-tetralones bearing isopropoxy or benzyloxy groups, synthetic key intermediates for phenolic antileukaemic benzo[c]phenanthridine alkaloids, from 2,4-diarylbutyric acid derivatives
Hisashi Ishii Ih-Sheng Chen Satoshi Ueki Takeshi Masuda Kenji Morita and Tsutomu Ishikawa
pg 2415; DOI:
10.1039/P19870002415
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Higher-carbon sugars. Part 8. The synthesis of some decitols via the epoxidation of unsaturated precursors
John S. Brimacombe Roderick Hanna and Abul K. M. S. Kabir
pg 2421; DOI:
10.1039/P19870002421
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On the role of leucine in terpenoid metabolism
Panayiotis Anastasis Isabel Freer Karl H. Overton Douglas Picken David S. Rycroft and Sheo Bux Singh
pg 2427; DOI:
10.1039/P19870002427
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Enhanced carbonyl reactivity and conformational effects in peri-dioxocycloalka[de]naphthalenes
David A. Jackson Donald C. C. Smith and C. Ian F. Watt
pg 2437; DOI:
10.1039/P19870002437
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The rearrangement of a tetrahydrobiphenylene derivative to a bridged benzocycloheptene
John W. Barton Judith A. K. Howard Michael K. Shepherd and Andrew M. Stringer
pg 2443; DOI:
10.1039/P19870002443
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Studies on the synthesis of linear aliphatic compounds. Part 2. The realisation of a strategy for repeated molecular doubling.
Eva Igner Oliver I. Paynter Derek J. Simmonds and Mark C. Whiting
pg 2447; DOI:
10.1039/P19870002447
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Studies on the synthesis of linear aliphatic compounds. Part. 3 The synthesis of paraffins with very long chains
Ilesh Bidd David W. Holdup and Mark C. Whiting
pg 2455; DOI:
10.1039/P19870002455
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Studies on the synthesis of linear aliphatic compounds. Part 4. An approach to long-chain paraffins with lateral side-chains
Emmanuel A. Adegoke Hogan Ephraim-Bassey David J. Kelly and Mark C. Whiting
pg 2465; DOI:
10.1039/P19870002465
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A three-step procedure for the conversion of -lactones into -lactones
Fritz Theil Burkhard Costisella Hans Groß Hans Schick and Sigfrid Schwarz
pg 2469; DOI:
10.1039/P19870002469
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Conversion of N-hydroxytryptophans into ,-dehydrotryptophan. An approach to the neoechinulin series
Ralf Plate Rutger J. F. Nivard and Harry C. J. Ottenheijm
pg 2473; DOI:
10.1039/P19870002473
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Conversion of N-hydroxytryptophan into -functionalised tryptophans. An approach to the sporidesmin series
Ralf Plate Marcel A. J. Akkerman Harry C. J. Ottenheijm and Jan M. M. Smits
pg 2481; DOI:
10.1039/P19870002481
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Application of a tandem electrocyclic [3,3]sigmatropic reaction of o-quinodimethane to the synthesis of calabar bean alkaloids. Part 2. First total synthesis of ()-geneserine
Kozo Shishido Kou Hiroya Hironori Komatsu Keiichiro Fukumoto and Tetsuji Kametani
pg 2491; DOI:
10.1039/P19870002491
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Use of the diazoalkane–thione reaction in the synthesis of a vinyltrimethylenemethane precursor
Richard J. Bushby and Stephen Mann
pg 2497; DOI:
10.1039/P19870002497
PDF
Formation of 2-acetylpyridines by the base-catalysed ring opening of dihydro-4H-furo[2,3-e]oxazines
Thomas L. Gilchrist Deborah Hughes Wayne Stretch and Ewan J. T. Chrystal
pg 2505; DOI:
10.1039/P19870002505
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Intramolecular cycloaddition of azoalkenes derived from terminal alkenoic and alkynoic acids
Thomas L. Gilchrist Robert C. Wasson Frank D. King and Gordon Wootton
pg 2511; DOI:
10.1039/P19870002511
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Formation of pyridazino[6,1-c][1,4]oxazin-8(7H)-ones by intramolecular cycloaddition of azoalkenes
Thomas L. Gilchrist Robert C. Wasson Frank D. King and Gordon Wootton
pg 2517; DOI:
10.1039/P19870002517
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Photochemical reactions of pyrimidinethiones with alkenes
Takehiki Nishio Masaru Fujisawa and Yoshimori Omote
pg 2523; DOI:
10.1039/P19870002523
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An unexpected double cycloaddition of [1,2,4]triazolo[1,5-a]pyrimidine N-ylide with activated acetylenes and alkenes
Mikio Hori Tadashi Kataoka Hiroshi Shimizu Eiji Imai Kiyomi Tanaka Kazuhiko Kimura Yoshinobu Hashimoto Satoshi Inagaki Naomi Goto and Masaru Kido
pg 2531; DOI:
10.1039/P19870002531
PDF
N-monomethylation of primary amines via intermediate benzothiazol-2(3H)-imines
Alan R. Katritzky Malgorzata Drewniak and Jose M. Aurrecoechea
pg 2539; DOI:
10.1039/P19870002539
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Electrophilic substitution in indoles. Part 15. The reaction between methylenedi-indoles and p-nitrobenzenediazonium fluoroborate
Anthony H. Jackson Noojaree Prasitpan Patrick V. R. Shannon and Alan C. Tinker
pg 2543; DOI:
10.1039/P19870002543
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The structure and synthesis of the novel orchid pigments dengibsin and dengibsinin
Melvyn V. Sargent
pg 2553; DOI:
10.1039/P19870002553
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Regioselective total synthesis of ()-berberastine
Elio Napolitano Guido Spinelli Rita Fiaschi and Antonio Marsili
pg 2565; DOI:
10.1039/P19870002565
PDF
Applications of the stereochemically-controlled Horner-Wittig reaction: synthesis of feniculin, (E)-non-6-en-1-ol, a pheromone of the mediterranean fruit fly, (E)- and (Z)-dec-5-en-1-ol, tri-substituted alkenes, and (Z)--bisabolene
Antony D. Buss Nicholas Greeves Ralph Mason and Stuart Warren
pg 2569; DOI:
10.1039/P19870002569
PDF
Allyl sulphide synthesis by phenylthio migration: relationship between stereochemistry of starting materials and regioselectivity of double bond formation
Varinder K. Aggarwal and Stuart Warren
pg 2579; DOI:
10.1039/P19870002579
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Azafluorenes containing two bridgehead nitrogen atoms
Terence R. Jones and Francis L. Rose
pg 2585; DOI:
10.1039/P19870002585
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Cycloadducts of nitrones with isocyanates; 1,2,4- or 1,3,4-oxadiazolidinones?
Anthony M. T. Bell Jonathan Bridges Richard Cross Christopher P. Falshaw Brian F. Taylor Giles A. Taylor Ian C. Whittaker and Michael J. Begley
pg 2593; DOI:
10.1039/P19870002593
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Substituted 4H-1-benzopyran-4-ones (chromones): synthesis via palladium-catalysed coupling of their halogeno derivatives with alkenes
Stephen G. Davies Bryan E. Mobbs and Christopher J. Goodwin
pg 2597; DOI:
10.1039/P19870002597
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Synthesis of allyl and dienyl sulphones via iodosulphonylation of conjugated dienes
José Barluenga José M. Martínez-Gallo Carmen Nájera Francisco J. Fañanás and Miguel Yus
pg 2605; DOI:
10.1039/P19870002605
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Photocycloaddition of quinoxalin-2-ones and benzoxazin-2-ones to aryl alkenes
Takehiko Nishio and Yoshimori Omote
pg 2611; DOI:
10.1039/P19870002611
PDF
Structural studies on bioactive-compounds. Part 7. The design and synthesis of -substituted serines as prospective inhibitors of serine hydroxymethyltransferase
Saul J. B. Tendler Michael D. Threadgill and Michael J. Tisdale
pg 2617; DOI:
10.1039/P19870002617
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Catalysis by palladium salts. Part 2. Palladium-catalysed carboxylation with carbon monoxide of aromatic compounds working under mild conditions
Renato Ugo and Anna Chiesa
pg 2625; DOI:
10.1039/P19870002625
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Di-heteroarylethyl enes: synthesis and donor properties
Anna Berlin Silvia Bradamante Raffaella Ferraccioli Giorgio A. Pagani and Franco Sannicolò
pg 2631; DOI:
10.1039/P19870002631
PDF
Stereospecific synthesis of a chiral intermediate for the preparation of thienamycin, penems, and carbapenems: use of the nitro group as a hydroxy protecting group
Gianfranco Cainelli Mauro Panunzio Tiziana Basile Alessandro Bongini Daria Giacomini and Giorgio Martelli
pg 2637; DOI:
10.1039/P19870002637
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Chemistry of silylated thioketones. Part 2. Cycloaddition reactions with 1,3-dienes
Bianca F. Bonini Alberto Lenzi Gaetano Maccagnani Gaetano Barbaro Patrizia Giorgianni and Dante Macciantelli
pg 2643; DOI:
10.1039/P19870002643
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Chemistry of silyl thioketones. Part 3. Cycloaddition reactions with heterodienes (-nitrosostyrene and ketene imines)
Patrizia Carisi Germana Mazzanti Paolo Zani Gaetano Barbaro Arturo Battaglia and Patrizia Giorgianni
pg 2647; DOI:
10.1039/P19870002647
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Steroids Part 22. Photochemistry of 5,6-epoxy-4,4-dimethylcholestan-3-ones and 5,6-epoxy-17-hydroxy-4,4-dimethylestran-3-ones
Richard W. G. Foster Syed H. Imam Brian A. Marples and George W. F. Stubbings
pg 2653; DOI:
10.1039/P19870002653
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Interaction of thiophene S,N-ylides with dimethyl acetylenedicarboxylate
Jan L. M. Dillen Otto Meth-Cohn and Gerda van Vurren
pg 2659; DOI:
10.1039/P19870002659
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Conformation dependent photochemistry of dienes. Substituent effects on the photochemical reactions of some 4-acyloxy-2-azabuta-1,3-dienes
Diego Armesto Mar G. Gallego and William M. Horspool
pg 2663; DOI:
10.1039/P19870002663
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New heterocyclization reactions for the preparation of fused [1,2,4]triazoles: synthesis of 1,2,4-triazolo[4,3-b][1,2,4]triazole derivatives from 4-amino-1,2,4-triazoles and carbodi-imides or via iminophosphoranes and disubstituted thioureas
Pedro Molina Mateo Alajarín Alicia Ferao and Me. Jesús Pérez de Vega
pg 2667; DOI:
10.1039/P19870002667
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The chemistry of N-substituted benzotriazoles. Part 7. The isomeric composition and mechanism of interconversion of some N-(aminomethyl)benzotriazole derivatives
Alan R. Katritzky Konstantina Yannakopoulou Wojciech Kuzmierkiewicz Jose M. Aurrecoechea Gus J. Palenik Anna E. Koziol Marian Szczesniak and Robert Skarjune
pg 2673; DOI:
10.1039/P19870002673
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The total synthesis of (–)-litsenolides C-1 and C-2
William W. Wood and Graham M. Watson
pg 2681; DOI:
10.1039/P19870002681
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The chemistry of aryl-lead(IV) tricarboxylates. Reaction with vinylogous -keto esters
Darren J. Ackland and John T. Pinhey
pg 2689; DOI:
10.1039/P19870002689
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Use of the electrophilic arylation reaction of aryl-lead triacetates in a synthesis of ()-lycoramine
Darren J. Ackland and John T. Pinhey
pg 2695; DOI:
10.1039/P19870002695
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Preparation of some allylic sulphones; base-catalysed isomerisation and deuteriation of cyclohex-2-enyl p-tolyl sulphones
Derek J. Knight Peter Lin Simon T. Russell and Gordon H. Whitham
pg 2701; DOI:
10.1039/P19870002701
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1,3-Rearrangements of some allylic sulphones
Derek J. Knight Peter Lin and Gordon H. Whitham
pg 2707; DOI:
10.1039/P19870002707
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The photolysis of trans-isohumulone to dehydrohumulinic acid, a key route to the development of sunstruck flavour in beer
Georges M. A. Bondeel Denis De Keukeleire and Maurice Verzele
pg 2715; DOI:
10.1039/P19870002715
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Enzyme-mediated H2O2 oxidation of (E)-stilbene-3,4-diol
Dervilla M. X. Donnelly Francis G. Murphy Judith Polonski and Thierry Prangé
pg 2719; DOI:
10.1039/P19870002719
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Flavonoids of Tephrosia procumbens—revised structure for praecansone A and conformation of praecansone B
G. Venkataratnam Erraguntla Venkata Rao and C. Vilain
pg 2723; DOI:
10.1039/P19870002723
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Synthesis of thiazolidinones from 1,4-dithiocyanatobut-2-enes and their use as masked 2-amino-1-mercaptobut-3-enes
Eatedal H. M. Abd Elall Mohamed I. Al Ashmawy and John M. Mellor
pg 2729; DOI:
10.1039/P19870002729
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Preparation of 1-nitro-1,3-dienes via nitrotrifluoroacetoxylation of 1,3-dienes
A. Jon Bloom and John M. Mellor
pg 2737; DOI:
10.1039/P19870002737
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The structure of citrinin in vivo
Jill Barber Julia L. Cornford Tina D. Howard and Derek Sharplese
pg 2743; DOI:
10.1039/P19870002743
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Synthesis of the trisaccharide component of the repeating unit of the capsular polysaccharide of Streptococcus pneumoniae type 19F
Luigi Panza Fiamma Ronchetti Giovanni Russo and Lucio Toma
pg 2745; DOI:
10.1039/P19870002745
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Reaction of di-t-butoxyethyne with Fe2(CO)9: X-ray crystal structure of (tetra-t-butoxycyclopentadienone)tricarbonyliron (0) and an improved formal synthesis of hydrocroconic acid and the croconate dianion
David Fornals Miquel A. Pericàs Fèlix Serratosa Jordi Vinaixa Manuel Font-Altaba and Xavier Solans
pg 2749; DOI:
10.1039/P19870002749
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Studies on the stereochemical control of fermenting baker's yeast mediated reductions: some 3- and 4-oxo esters
Ada Manzocchi Rosangela Casati Alberto Fiecchi and Enzo Santaniello
pg 2753; DOI:
10.1039/P19870002753
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Dialkylcarbamoyl(diaryl)iodanes
Elvira Kotali and Anastassios Varvoglis
pg 2759; DOI:
10.1039/P19870002759
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The shikimate pathway. Part 7. Chorismate mutase: towards an enzyme model
Trevor I. Richards Keith Layden Edward E. Warminski Peter J. Milburn and Edwin Haslam
pg 2765; DOI:
10.1039/P19870002765
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Metabolism of 2,4,4-trihydroxychalcone in Amorpha fruticosa seedlings; structure and role of chalaurenol, a novel heterocyclic enol ether formed by enzymic oxidation
Michael J. Begley Leslie Crombie A. Martin London John Savin and Donald A. Whiting
pg 2775; DOI:
10.1039/P19870002775
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Synthesis of 4-O-methyl- and 4,6-di-O-methyl-chalaurenol
Leslie Crombie Anne P. Ryan Donald A. Whiting and Samuel O. Yeboah
pg 2783; DOI:
10.1039/P19870002783
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Asymmetric induction in addition of N-nitrenes to alkenes: 2-(chiral)substituted benzimidazole-derived N-nitrene additions to alkenes
Robert S. Atkinson and Gary Tughan
pg 2787; DOI:
10.1039/P19870002787
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Asymmetric induction in addition of N-nitrenes to alkenes: oxidation of 3-amino-2-(1,2,2-trimethylpropyl)quinazolin-4(3H)-one in the presence of -methylene--butyrolactone: conformational analysis of the aziridines formed and comparison with alkanoylated cyclopropylamines
Robert S. Atkinson and Gary Tughan
pg 2797; DOI:
10.1039/P19870002797
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Chiral aziridination of ,-unsaturated esters and ketones using N-nitrenes in the presence of trifluoroacetic acid
Robert S. Atkinson and Gary Tughan
pg 2803; DOI:
10.1039/P19870002803
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Medicinal plants of Southern Africa. Part 1. Dimeric chalcone-based pigments from Brackenridgea zanguebarica
Siegfried E. Drewes Neale A. Hudson Robert B. Bates and Gary S. Linz
pg 2809; DOI:
10.1039/P19870002809
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Boron trifluoride-promoted reaction of benzenesulphenanilides with alkenes in acetonitrile and benzonitrile: amidino- and amido-sulphenylation of alkenes
Luisa Benati P. Carlo Montevecchi and Piero Spagnolo
pg 2815; DOI:
10.1039/P19870002815
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Radical-nucleophilic substitution (SRN1) reactions. Part 5. Anions of nitroimidazoles in SRN1 and oxidative addition reactions
Adelaide T. O. M. Adebayo W. Russell Bowman and W. G. Salt
pg 2819; DOI:
10.1039/P19870002819
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Synthesis of [6](2,4)pyridinophanes
Dashyant Dhanak and Colin B. Reese
pg 2829; DOI:
10.1039/P19870002829
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Transformation of santonin into(+)-deoxyvernolepin and related dilactones
Masataka Watanabe and Akira Yoshikoshi
pg 2833; DOI:
10.1039/P19870002833
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Novel heterocyclic systems. Part 28. Preparation and characterization of the 1,6-, 1,7-, 1,8-, and 1,9-diazaphenoxaselenines: an unexpected divergence between closely related sulphur and selenium systems
Keith Smith Ian Matthews and Gary E. Martin
pg 2839; DOI:
10.1039/P19870002839
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Facile and stereospecific synthesis of (S)- and (R)-[2-2H]isopentenyl pyrophosphates
Takayuki Suga Shinji Ohta and Tatsuya Ohmoto
pg 2845; DOI:
10.1039/P19870002845
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Studies on terpenoids and steroids. Part 10. Structures of four new natural phenol is D:A-friedo-24-noroleanane triterpenoids
Chandra B. Gamlath Kamal B. Gunaherath and A. A. Leslie Gunatilaka
pg 2849; DOI:
10.1039/P19870002849
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Dienone-phenol rearrangement of naphthalenetriones. A route to 10-acetoxy5,6,7,8-tetra hydrophenanthrene-1,4-diones
Raúl Cassis Mónica Scholz Ricardo Tapia and Jaime A. Valderrama
pg 2855; DOI:
10.1039/P19870002855
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Corrigendum
Girolamo Cirrincione Gaetano Dattolo Anna Maria Almerico Enrico Aiello R. Alan Jones Helen M. Dawes and Michael B. Hursthouse
pg 2861; DOI:
10.1039/P19870002861
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Instructions for authors (1987)

pg v; DOI:
10.1039/P1987000000v
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IUPAC publications on nomenclature and symbolism

pg xx; DOI:
10.1039/P198700000xx
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